1,4-双(二甲基羟基硅基)苯合成路线 （共 5 条）
反应条件
water in tetrahydrofuran T=20°C; 3 h;
参考文献
John, Jubi; Gravel, Edmond; Hagege, Agnes; Li, Haiyan; Gacoin, Thierry; Doris, Eric
Angewandte Chemie - International Edition, 2011 , vol. 50, # 33 p. 7533 - 7536
反应条件
1: With 2,2,6,6-tetramethyl-piperidine-N-oxyl; potassium bromide in acetone T=20°C; 0.166667 h; 2: With sodium hypochlorite; sodium hydrogencarbonate in water; acetone T=20°C; 1 h;
参考文献
Takeda, Daisuke; Oyama, Ryo; Yamada, Shozo
Chemistry Letters, 2009 , vol. 38, # 6 p. 532 - 533
反应条件
sodium hydroxide in methanol; ethanol
参考文献
Breed,L.W.; Elliott,R.L.
Journal of Organometallic Chemistry, 1967 , vol. 9, p. 188 - 192
反应条件
1: (i) Mg, THF, (ii) /BRN= 1733726/ 2: aq. NaOH / ethanol; methanol View Scheme
参考文献
Breed,L.W.; Elliott,R.L.
Journal of Organometallic Chemistry, 1967 , vol. 9, p. 188 - 192
反应条件
sodium hydroxide in sodium hydroxide; diethyl ether (CH3)2ClSiC6H4SiCl(CH3)2 and equival. amt. of aq. NaOH in ether at about 0°C;; crystn. from ether or by addn. of C6H6 to the ether soln.;;
参考文献
Gmelin Handbook: Si: MVol.C, 88, page 240 - 242
