Hartwig, John F.; Muhoro, Clare N.; He, Xiaoming; Eisenstein, Odile; Bosque, Ramon; Maseras, Feliu
Journal of the American Chemical Society, 1996 , vol. 118, # 44 p. 10936 - 10937
Hartwig, John F.; Muhoro, Clare N.; He, Xiaoming; Eisenstein, Odile; Bosque, Ramon; Maseras, Feliu
Journal of the American Chemical Society, 1996 , vol. 118, # 44 p. 10936 - 10937
(S)-3,3-diphenyl-1-methyltetrahydro-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborol in various solvent(s) T=-78°C; 2.7 h; Title compound not separated from byproducts;
参考文献
UNIVERSITY OF PITTSBURGH-OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATION
Patent: WO2009/31999 A1, 2009 ;
Location in patent: Page/Page column 50 ;
1: With (4R,5R)-DIOP; [{RhCl(cod)}2] in tetrahydrofuran T=20°C; 4 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran; water optical yield given as percent ee;
参考文献
Marques, Carolina S.; Burke, Anthony J.
Synthetic Communications, 2008 , vol. 38, # 23 p. 4207 - 4214
in diethylene glycol dimethyl ether to a soln. of NaBH4 (22.2 mmol) in diglyme was added dropwise with stirring under N2 a soln. of catecholatoborane (44.4 mmol) in diglyme; B2H6 was absorbed in acetone (for 16 h);; after evapn. of the solvent the solid residue was dried at 100°C(1E-2 mm Hg);;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1689 - 1692
