1-氯-3,3,3-三氟丙烯合成路线 （共 42 条）
反应条件
hydrogen fluoride; oxygen T=350°C; 0.3 h; Reagent/catalystTime; Overall yield = 94 percentChromat.; chemoselective reaction;
参考文献
DAIKIN INDUSTRIES, LTD.; KARUBE, Daisuke; CHAKI, Takehiro; NISHIUMI, Masami; SHIBANUMA, Takashi; ARAI, Masashi
Patent: WO2013/111911 A1, 2013 ;
Location in patent: Page/Page column 29 ;
反应条件
hydrogen fluoride; fluorided chromium-carrying activated carbon T=400°C; 3 h; Inert atmosphere; Product distribution / selectivity;
参考文献
Central Glass Company, Limited
Patent: US2012/123172 A1, 2012 ;
Location in patent: Page/Page column 13 ;
反应条件
potassium hydroxide in water T=70°C; 6 h;
参考文献
Komata, Takeo; Akiba, Shinya; Hosoi, Kenji; Ogura, Katsuyuki
Journal of Fluorine Chemistry, 2008 , vol. 129, # 1 p. 35 - 39
反应条件
ammonium formate; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=-30 - 100°C; P=9308.91 - 10343.2 Torr; 24 h;
参考文献
Honeywell International Inc.
Patent: US6958424 B1, 2005 ;
Location in patent: Page/Page column 8 ;
反应条件
hydrogen; 0.5 Ru/activated carbon T=170°C; 1 h; Inert atmosphere; Product distribution / selectivity;
参考文献
Central Glass Company, Limited
Patent: EP2514735 A1, 2012 ;
Location in patent: Page/Page column 8 ;
反应条件
hydrogen fluoride T=80°C; P=775.743 Torr; 0.00127778 - 0.00761111 h; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US2005/20862 A1, 2005 ;
Location in patent: Page 3; 4 ;
反应条件
hydrogen fluoride; chlorine; SbCl5 on Shiro Sagi G2X carbon activated by HF, Cl2 at 100 C T=70°C; P=2327.23 Torr; 0.00319444 h; Gas phase; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US7829748 B1, 2010 ;
Location in patent: Page/Page column 5-6 ;
反应条件
potassium hydroxide in water T=70°C; 6 h;
参考文献
Komata, Takeo; Akiba, Shinya; Hosoi, Kenji; Ogura, Katsuyuki
Journal of Fluorine Chemistry, 2008 , vol. 129, # 1 p. 35 - 39
反应条件
hydrogen fluoride
T=80°C; P=775.743 Torr; 0.00127778 - 0.00761111 h; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US2005/20862 A1, 2005 ;
Location in patent: Page 3; 4 ;
反应条件
hydrogen fluoride; oxygen
T=350°C; 0.3 h; Reagent/catalystTime; Overall yield = 94 percentChromat.; chemoselective reaction;
参考文献
DAIKIN INDUSTRIES, LTD.; KARUBE, Daisuke; CHAKI, Takehiro; NISHIUMI, Masami; SHIBANUMA, Takashi; ARAI, Masashi
Patent: WO2013/111911 A1, 2013 ;
Location in patent: Page/Page column 29 ;
