雄甾-3-酮-4-烯-17bata-羧酸甲酯合成路线 （共 22 条）
反应条件
cyclohexanone; aluminum isopropoxide in toluene
参考文献
Fei, Xiang-Shu; Tian, Wei-Sheng; Chen, Qing-Yun
Bioorganic and Medicinal Chemistry Letters, 1997 , vol. 7, # 24 p. 3113 - 3118
反应条件
1: I2 / 1.5 h / Heating 2: methanol / 1 h / Heating 3: 70.62 percent / Al(i-PrO)3 / cyclohexanone; toluene / 4 h / Heating View Scheme
参考文献
Rey, Jullien; O'Riordan, Timothy J. C.; Hu, Haipeng; Snyder, James P.; White, Andrew J. P.; Barrett, Anthony G. M.
European Journal of Organic Chemistry, 2012 , # 20 p. 3781 - 3794
反应条件
1: methanol / 1 h / Heating 2: 70.62 percent / Al(i-PrO)3 / cyclohexanone; toluene / 4 h / Heating View Scheme
参考文献
Rey, Jullien; O'Riordan, Timothy J. C.; Hu, Haipeng; Snyder, James P.; White, Andrew J. P.; Barrett, Anthony G. M.
European Journal of Organic Chemistry, 2012 , # 20 p. 3781 - 3794
反应条件
1: cesium fluoride / dimethylformamide / 24 h / 20 °C 2: 3.1 g / cyclohexanone; aluminium isopropoxide / toluene / Heating View Scheme
参考文献
Ruzicka; Plattner; Balla
Helvetica Chimica Acta, 1942 , vol. 25, p. 65,71
反应条件
sodium azide in methanol T=50°C; 1.5 h;
参考文献
Annen, Klaus; Hofmeister, Helmut; Laurent, Henry; Hoyer, Georg-Alexander
Liebigs Annalen der Chemie, 1989 , p. 991 - 996
反应条件
1: 68.3 percent / H2O2, 0.2N NaOH / hemin / methanol / 4 h / 20 °C View Scheme
参考文献
Ohkoshi, Atsushi; Abe, Kazuya; Kodera, Yoh; Inada, Yuji
Agricultural and Biological Chemistry, 1989 , vol. 53, # 7 p. 2013 - 2014
反应条件
1: 1.) NaOBr, 2.) HCl / 1.) dioxane, water 2: 82 percent / p-toluenesulfonic acid / 5 h / Heating 3: 87 percent / Al(i-PrO)3, cyclohexanone / toluene View Scheme
参考文献
Shen, Li-Qun; Huang, Su-Yu; Tang, Yong; Lei, Fu-Hou
Steroids, 2012 , vol. 77, # 13 p. 1398 - 1402
反应条件
1: 73 percent / DMAP / bis-(2-methoxy-ethyl) ether / 17 h / Ambient temperature 2: 48 percent / NaN3 / 22 h / Ambient temperature View Scheme
参考文献
Annen, Klaus; Hofmeister, Helmut; Laurent, Henry; Hoyer, Georg-Alexander
Liebigs Annalen der Chemie, 1989 , p. 991 - 996
参考文献
Ohkoshi, Atsushi; Abe, Kazuya; Kodera, Yoh; Inada, Yuji
Agricultural and Biological Chemistry, 1989 , vol. 53, # 7 p. 2013 - 2014
反应条件
1: bromine 2: NaI; acetone / Erwaermen des Reaktionsprodukts mit Zink-Pulver und Aethanol View Scheme
参考文献
Sallmann; Tamm
Helvetica Chimica Acta, 1956 , vol. 39, p. 1340,1360
