9-(二乙氨基)螺[12H-苯并[A]占吨-12,1,(3,H)-异苯并呋喃]-3,-酮合成路线 （共 23 条）
反应条件
1: With methanesulfonic acid T=20 - 25°C; 24 h; 2: With sodium hydroxide in water T=75 - 80°C; 4 h;
参考文献
Azizian, Farid; Field, Amanda J.; Heron, B. Mark; Kilner, Colin
Chemical Communications, 2012 , vol. 48, # 5 p. 750 - 752
反应条件
tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; [(t-Bu)3PH]BF4 in toluene T=70°C; 24 h; Inert atmosphere;
参考文献
Azizian, Farid; Field, Amanda J.; Griffiths, John; Heron, B. Mark
Dyes and Pigments, 2012 , vol. 92, # 1 p. 524 - 530
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in ethanol; toluene Suzuki coupling; 22 h; RefluxInert atmosphere;
参考文献
Azizian, Farid; Field, Amanda J.; Heron, B. Mark; Kilner, Colin
Chemical Communications, 2012 , vol. 48, # 5 p. 750 - 752
反应条件
1.1: toluene / Reflux 2.1: methanesulfonic acid / 24 h / 20 - 25 °C 2.2: 4 h / 75 - 80 °C View Scheme
参考文献
Azizian, Farid; Field, Amanda J.; Heron, B. Mark; Kilner, Colin
Chemical Communications, 2012 , vol. 48, # 5 p. 750 - 752
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in ethanol; toluene Suzuki coupling; 22 h; RefluxInert atmosphere;
参考文献
Azizian, Farid; Field, Amanda J.; Heron, B. Mark; Kilner, Colin
Chemical Communications, 2012 , vol. 48, # 5 p. 750 - 752
反应条件
1.1: toluene / Reflux 2.1: methanesulfonic acid / 24 h / 20 - 25 °C 2.2: 4 h / 75 - 80 °C View Scheme
参考文献
Azizian, Farid; Field, Amanda J.; Griffiths, John; Heron, B. Mark
Dyes and Pigments, 2012 , vol. 92, # 1 p. 524 - 530
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in ethanol; toluene Suzuki coupling; 22 h; RefluxInert atmosphere;
参考文献
Azizian, Farid; Field, Amanda J.; Heron, B. Mark; Kilner, Colin
Chemical Communications, 2012 , vol. 48, # 5 p. 750 - 752
反应条件
1.1: toluene / Reflux 2.1: sulfuric acid / 4 h / 120 - 125 °C 2.2: 0.5 h / Reflux 3.1: tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; [(t-Bu)3PH]BF4 / toluene / 24 h / 70 °C / Inert atmosphere View Scheme
参考文献
Azizian, Farid; Field, Amanda J.; Griffiths, John; Heron, B. Mark
Dyes and Pigments, 2012 , vol. 92, # 1 p. 524 - 530
反应条件
1.1: sulfuric acid / 4 h / 120 - 125 °C 1.2: 0.5 h / Reflux 2.1: tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; [(t-Bu)3PH]BF4 / toluene / 24 h / 70 °C / Inert atmosphere View Scheme
参考文献
Azizian, Farid; Field, Amanda J.; Griffiths, John; Heron, B. Mark
Dyes and Pigments, 2012 , vol. 92, # 1 p. 524 - 530
反应条件
1.1: toluene / Reflux 2.1: sulfuric acid / 4 h / 120 - 125 °C 2.2: 0.5 h / Reflux 3.1: tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; [(t-Bu)3PH]BF4 / toluene / 24 h / 70 °C / Inert atmosphere View Scheme
参考文献
Azizian, Farid; Field, Amanda J.; Griffiths, John; Heron, B. Mark
Dyes and Pigments, 2012 , vol. 92, # 1 p. 524 - 530
