(2E)-3-环己基-2-丙烯酸甲酯合成路线 （共 25 条）
反应条件
(Z)-MeO2CCHCHI in dimethyl sulfoxide; benzene
Irradiation (UV/VIS); mercurial and organic compound dissolved in nitrogen purged solvent, irradn. (350-nm Rayonet photoreactor, 35-40°C, 6h);; mixt. poured into water; extn. with benzene; ext. washed (aq. Na2S2O3), dried (Na2SO4) and concd. (vacuum); yield (detd. by (1)H NMR): 45percent E and Z isomers; E/Z ratio: 0.9 (detd. by GLC);;
参考文献
Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.; Pla-Dalmau, Anna; Khanna, Rajive K.
Journal of the American Chemical Society, 1988 , vol. 110, # 11 p. 3530 - 3538
反应条件
copper(l) iodide; BuTeBu
T=50°C;
参考文献
Zhou, Zhang-Lin; Huang, Yao-Zeng; Shi, Li-Lan
Tetrahedron, 1993 , vol. 49, # 31 p. 6821 - 6830
反应条件
in dimethylsulfoxide-d6; dichloromethane
T=35 - 40°C; 24 h; Irradiation; Yield given. Yields of byproduct given;
参考文献
Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.; Pla-Dalmau, Anna; Khanna, Rajive K.
Journal of the American Chemical Society, 1988 , vol. 110, # 11 p. 3530 - 3538
反应条件
in dimethyl sulfoxide; benzene
T=35 - 40°C; 6 h; Irradiation; Yield given. Yields of byproduct given;
参考文献
Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.; Pla-Dalmau, Anna; Khanna, Rajive K.
Journal of the American Chemical Society, 1988 , vol. 110, # 11 p. 3530 - 3538
反应条件
in dimethyl sulfoxide; benzene
T=35 - 40°C; 6 h; Irradiation; Yield given. Yields of byproduct given;
参考文献
Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.; Pla-Dalmau, Anna; Khanna, Rajive K.
Journal of the American Chemical Society, 1988 , vol. 110, # 11 p. 3530 - 3538
反应条件
1: C17H18NO4P With n-butyllithium in tetrahydrofuran; hexane
T=-35°C; 0.5 h;
2: cyclohexanecarbaldehyde in tetrahydrofuran; hexane
T=-70°C; Further stages. Title compound not separated from byproducts.;
参考文献
Perez; Ortiz
Chemical Communications, 2000 , # 20 p. 2029 - 2030
反应条件
pentacarbonyliron(0)
T=0°C; 0.5 h; UV-irradiationPhotolysis;
参考文献
Mathur, Pradeep; Joshi, Raj Kumar; Jha, Badrinath; Singh, Amrendra K.; Mobin, Shaikh M.
Journal of Organometallic Chemistry, 2010 , vol. 695, # 24 p. 2687 - 2694
反应条件
silica gel in hexane
T=25°C; 2 h; Yield given. Yields of byproduct given;
参考文献
Patil, Vijay J.; Maevers, Ursula
Tetrahedron Letters, 1996 , vol. 37, # 8 p. 1281 - 1284
反应条件
Grubb's 2nd generation catalyst in dichloromethane
Heating;
参考文献
Scholte, Andrew A.; Mi, Hyun An; Snapper, Marc L.
Organic Letters, 2006 , vol. 8, # 21 p. 4759 - 4762
反应条件
lithium chloride; palladium dichloride
T=-78°C;
参考文献
Larock,R.C.
Journal of Organic Chemistry, 1975 , vol. 40, # 22 p. 3237 - 3242
