2,4,6-三甲基苯溴化镁合成路线 （共 186 条）
反应条件
1: diethyl ether 2: aq.-ethanolic KOH-solution View Scheme
参考文献
Lapkin
Zhurnal Obshchei Khimii, 1946 , vol. 16, p. 729,732,733
Chem. Zentralbl., 1947 , vol. 118, p. 1218
反应条件
1: superheavy water / 1 h / 20 °C / Inert atmosphere 2: gold(III) chloride / 1,2-dichloro-ethane / 24 h / 110 °C View Scheme
参考文献
Qiu, Di; Zheng, Zhitong; Mo, Fanyang; Xiao, Qing; Tian, Yu; Zhang, Yan; Wang, Jianbo
Organic Letters, 2011 , vol. 13, # 19 p. 4988 - 4991
反应条件
1: 2,4,6-trimethylphenylmagnesium bromide With PEPPSITM-IPr; zinc(II) chloride in tetrahydrofuran T=23°C; 0.333333 h; Inert atmosphere; 2: 1-bromo-2,6-dimethyl-benzene in tetrahydrofuran T=70°C; 2.5 h; Inert atmosphere;
参考文献
Calimsiz, Selcuk; Sayah, Mahmoud; Mallik, Debasis; Organ, Michael G.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 11 p. 2014 - 2017
参考文献
Kohler, Erickson
Journal of the American Chemical Society, 1931 , vol. 53, p. 2301,2307
反应条件
reagiert analog mit 2.3.5.6-Tetramethyl-phenylmagnesiumbromid und Pentamethyl-phenylmagnesiumbromid;
参考文献
Lapkin; Schkljajew; Schkljajewa
Zhurnal Obshchei Khimii, 1940 , vol. 10, p. 1449,1451
Chem. Zentralbl., 1941 , vol. 112, # II p. 332
Full Text Show Details
Lapkin
Zhurnal Obshchei Khimii, 1946 , vol. 16, p. 729,732,733
Chem. Zentralbl., 1947 , vol. 118, p. 1218
反应条件
tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine in tetrahydrofuran T=20°C;
参考文献
Angewandte Chemie - International Edition, , vol. 45, # 14 p. 2289 - 2292
反应条件
in tetrahydrofuran Grignard reaction;
参考文献
Chemical Communications, , # 20 p. 2066 - 2068
反应条件
anhydrous iron chloride; 1,2-dichloro-ethane in tetrahydrofuran T=25°C; 0.5 h; Ionic liquidInert atmosphere;
参考文献
Kude, Keisuke; Hayase, Shuichi; Kawatsura, Motoi; Itoh, Toshiyuki
Heteroatom Chemistry, 2011 , vol. 22, # 3-4 p. 397 - 404
反应条件
biscyclopentadienyliron(II); bis(1,3-dimesityl-1H-imidazol-2(3H)-ylidene)nickel(I) bromide in diethyl ether; benzene-d6 T=20°C; 0.0833333 h; Inert atmosphere;
参考文献
Zhang, Kainan; Conda-Sheridan, Martin; R. Cooke, Shayna; Louie, Janis
Organometallics, 2011 , vol. 30, # 9 p. 2546 - 2552
参考文献
McElvain; Venerable
Journal of the American Chemical Society, 1950 , vol. 72, p. 1661,1667
