2,4,6-三甲基苯溴化镁合成路线 （共 186 条）
参考文献
Carre
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1910 , vol. 151, p. 150
Bulletin de la Societe Chimique de France, 1910 , vol. <4> 7, p. 842
反应条件
1: diethyl ether 2: thionyl chloride View Scheme
参考文献
Barnes
Organic Syntheses, 1941 , vol. 21, p. 77
反应条件
in tetrahydrofuran under N2 or Ar, ice-acetone bath, -78°C, dropwise addn. of BF3*(C2H5)2O, stirred for 12 h, 25°C; filtered under N2, solvent removed in vac., distillation;
参考文献
Eisch, John J.; Shafii, Babak; Odom, Jerome D.; Rheingold, Arnold L.
Journal of the American Chemical Society, 1990 , vol. 112, # 5 p. 1847 - 1853
反应条件
diethyl ether; boron trifluoride diethyl etherate; toluene
参考文献
Brown; Dodson
Journal of the American Chemical Society, 1957 , vol. 79, p. 2302,2304
反应条件
in diethyl ether addn. of MesMgBr in Et2O over a period of 1.5 h to BF3 in Et2O, refluxed for 3 h; removal of solvent in vac., sublimation (100°C, 1E-1 Torr);
参考文献
Chisholm, Malcolm H.; Folting, Kirsten; Haubrich, Scott T.; Martin, James D.
Inorganica Chimica Acta, 1993 , vol. 213, p. 17 - 24
反应条件
1: With tributyltin chloride in tetrahydrofuran T=-78 - 23°C; Inert atmosphere; 2: With silver trifluoromethanesulfonate; F-TEDA-PF6 in acetone T=23°C; 0.333333 h; Inert atmosphere; regiospecific reaction;
参考文献
Tang, Pingping; Ritter, Tobias
Tetrahedron, 2011 , vol. 67, # 24 p. 4449 - 4454
参考文献
Spielman; Schmidt
Journal of the American Chemical Society, 1937 , vol. 59, p. 2010
反应条件
in tetrahydrofuran T=20°C; Condensation; 3 h;
参考文献
Rigon; Ranaivonjatovo; Escudie
Phosphorus, Sulfur and Silicon and Related Elements, 1999 , vol. 152, p. 153 - 167
参考文献
Lapkin; Ponomarewa; Pinegina
Zhurnal Obshchei Khimii, 1952 , vol. 22, p. 1365
Chem.Abstr., 1953 , p. 4861
反应条件
1: dioxane / tetrahydrofuran View Scheme
参考文献
Machelett, B.
Zeitschrift fuer Chemie (Stuttgart, Germany), 1976 , vol. 16, p. 116 - 117
