Noorduin, Wim L.; Kaptein, Bernard; Meekes, Hugo; Enckevort, Willem J. P. van; Kellogg, Richard M.; Vlieg, Elias
Angewandte Chemie, International Edition, 2009 , vol. 48, p. 4581 - 4583
Angewandte Chemie, 2009 , vol. 121, p. 4651 - 4653
(+)-(2-(tert-butyldimethylsilyloxymethyl)pyrrolyl)(pentamethylcyclpentadienyl)iron(II); 2,6-di-tert-butylpyridin-1-ium trifluoromethanesulfonate in acetone
T=-78°C; 24 h; Yield givenYields of byproduct given. Title compound not separated from byproducts;
参考文献
Hodous, Brian L.; Ruble, J. Craig; Fu, Gregory C.
Journal of the American Chemical Society, 1999 , vol. 121, # 11 p. 2637 - 2638
1.1: LDA / tetrahydrofuran / 0.5 h / 0 °C
1.2: tetrahydrofuran / 2 h / 0 - 20 °C
2.1: (R)-BINOL-SnCl4 / toluene; CH2Cl2 / 1 h / -78 °C
2.2: aq. HCl / toluene; CH2Cl2
View Scheme
参考文献
Nakamura, Shingo; Kaneeda, Masanobu; Ishihara, Kazuaki; Yamamoto, Hisashi
Journal of the American Chemical Society, 2000 , vol. 122, # 34 p. 8120 - 8130
1.1: (R)-BINOL-SnCl4 / toluene; CH2Cl2 / 1 h / -78 °C
1.2: aq. HCl / toluene; CH2Cl2
View Scheme
参考文献
Nakamura, Shingo; Kaneeda, Masanobu; Ishihara, Kazuaki; Yamamoto, Hisashi
Journal of the American Chemical Society, 2000 , vol. 122, # 34 p. 8120 - 8130