苯并[b][1]苯并硫杂卓合成路线 （共 10 条）
反应条件
sodium sulfide nonahydrate in 1-methyl-pyrrolidin-2-one
T=180°C; 16 h; Inert atmosphere;
参考文献
Saito, Masahiko; Yamamoto, Tatsuya; Osaka, Itaru; Miyazaki, Eigo; Takimiya, Kazuo; Kuwabara, Hirokazu; Ikeda, Masaaki
Tetrahedron Letters, 2010 , vol. 51, # 40 p. 5277 - 5280
反应条件
potassium carbonate in N,N-dimethyl-formamide
12 h; Heating;
参考文献
Sindelar; Holubek; Ryska; et al.
Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # 4 p. 1187 - 1211
反应条件
pyridine; titanium tetrachloride; zinc
McMurry coupling; 4 h; Heating;
参考文献
Shirani, Hamid; Janosik, Tomasz
Journal of Organic Chemistry, 2007 , vol. 72, # 23 p. 8984 - 8986
反应条件
sodium sulfide nonahydrate; sulfur in 1-methyl-pyrrolidin-2-one
T=180°C; 16 h; Inert atmosphere;
参考文献
Saito, Masahiko; Yamamoto, Tatsuya; Osaka, Itaru; Miyazaki, Eigo; Takimiya, Kazuo; Kuwabara, Hirokazu; Ikeda, Masaaki
Tetrahedron Letters, 2010 , vol. 51, # 40 p. 5277 - 5280
反应条件
tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; N-[2'-(dicyclohexylphosphino)-1,1'-biphenyl-2-yl]-N,N-dimethylamine in 1,4-dioxane
T=180°C; Mizoroki-Heck cyclization; 0.5 h; Inert atmosphereMicrowave irradiation;
参考文献
Jepsen, Tue Heesgaard; Larsen, Mogens; Jorgensen, Morten; Nielsen, Mogens Brondsted
Synlett, 2012 , # 3 p. 418 - 422
反应条件
sodium sulfide nonahydrate; sulfur in 1-methyl-pyrrolidin-2-one
T=180°C; 16 h; Inert atmosphere;
参考文献
Saito, Masahiko; Yamamoto, Tatsuya; Osaka, Itaru; Miyazaki, Eigo; Takimiya, Kazuo; Kuwabara, Hirokazu; Ikeda, Masaaki
Tetrahedron Letters, 2010 , vol. 51, # 40 p. 5277 - 5280
反应条件
potassium cyanide in N,N-dimethyl-formamide
T=120°C; 7 h; Yield given;
参考文献
Sindelar; Holubek; Ryska; et al.
Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # 4 p. 1187 - 1211
反应条件
1.1: potassium tert-butylate / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere
1.2: 0 - 20 °C / Inert atmosphere
2.1: tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri-cyclo-hexyl-phosphine / toluene / 0.5 h / 180 °C / Inert atmosphere; Microwave irradiation
View Scheme
参考文献
Jepsen, Tue Heesgaard; Larsen, Mogens; Jorgensen, Morten; Nielsen, Mogens Brondsted
Synlett, 2012 , # 3 p. 418 - 422
反应条件
1.1: potassium carbonate / acetonitrile / 0.5 h / 100 °C / Microwave irradiation
2.1: potassium tert-butylate / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere
2.2: 0 - 20 °C / Inert atmosphere
3.1: tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri-cyclo-hexyl-phosphine / toluene / 0.5 h / 180 °C / Inert atmosphere; Microwave irradiation
View Scheme
参考文献
Jepsen, Tue Heesgaard; Larsen, Mogens; Jorgensen, Morten; Nielsen, Mogens Brondsted
Synlett, 2012 , # 3 p. 418 - 422
反应条件
1.1: potassium carbonate / acetonitrile / 0.5 h / 100 °C / Microwave irradiation
2.1: potassium tert-butylate / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere
2.2: 0 - 20 °C / Inert atmosphere
3.1: tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri-cyclo-hexyl-phosphine / toluene / 0.5 h / 180 °C / Inert atmosphere; Microwave irradiation
View Scheme
参考文献
Jepsen, Tue Heesgaard; Larsen, Mogens; Jorgensen, Morten; Nielsen, Mogens Brondsted
Synlett, 2012 , # 3 p. 418 - 422
