in neat (no solvent, gas phase) byproducts: NaI; iodine atom and supersonic Na vapor beam, vac.; reaction detected by chemiluminescence measurement;
参考文献
Cobb, S. H.; Woodward, J. R.; Gole, J. L.
Chemical Physics Letters, 1989 , vol. 156, p. 197 - 203
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反应条件
in gaseous matrix expanding of Na vapor (produced on evaporation of Na from stainless steel oven, 300 - 400°C) and Ne in He; not isolated;
参考文献
Lapatovich, Walter P.; Ahmad-Bitar, Riad; Moskowitz, Philip E.; Renhorn, Ingemar; Gottscho, Richard A.; Pritchard, David E.
Journal of Chemical Physics, 1980 , vol. 73, # 11 p. 5419 - 5431
in gas high-density alkali jet device at about 710K;; not isolated; detected by near IR-, thermal emission- and laser-inducedfluorescence spectroscopy;;
参考文献
Huennekens, J.; Walker, T. G.; McClain, S. C.
Journal of Chemical Physics, 1985 , vol. 83, # 10 p. 4949 - 4957
carbon tetrafluoride in neat (no solvent) crossing Na vapour beam at 600 K (E-4 torr) and F atom beam, produced by microwave discharge of CF4; monitored by chemilumescence spectroscopy;
参考文献
Polanyi, J. C.; Reiland, W.; Stanners, C. D.; Thomas, D. F.; Visticot, J.-P.
Journal of Physical Chemistry, 1989 , vol. 93, # 12 p. 4723 - 4729
