5H-二苯并[a,d]环庚烯合成路线 （共 55 条）
反应条件
in neat (no solvent)
T=430°C; P=0.05 Torr; 1 h; Product distribution;
参考文献
Pomerantz, Martin; Combs, Gerald L.; Fink, Rina
Journal of Organic Chemistry, 1980 , vol. 45, # 1 p. 143 - 149
反应条件
1: polyphosphoric acid
2: HNO3
3: CCl4; bromine / Irradiation.Erhitzen des Reaktionsprodukts mit Propan-1,3-diol
4: DMF; aqueous Na2S2 / Erwaermen des Reaktionsprodukts mit NaNO2 und aethanol. H2SO4
5: N2H4+H2O; KOH; propane-1,3-diol
6: Diazotization.anschliessend Behandeln mit wss. H3PO2
View Scheme
参考文献
Campbell et al.
Helvetica Chimica Acta, 1953 , vol. 36, p. 1489,1495
反应条件
1: N2H4+H2O; KOH; propane-1,3-diol
2: Diazotization.anschliessend Behandeln mit wss. H3PO2
View Scheme
参考文献
Campbell et al.
Helvetica Chimica Acta, 1953 , vol. 36, p. 1489,1495
反应条件
1: DMF; aqueous Na2S2 / Erwaermen des Reaktionsprodukts mit NaNO2 und aethanol. H2SO4
2: N2H4+H2O; KOH; propane-1,3-diol
3: Diazotization.anschliessend Behandeln mit wss. H3PO2
View Scheme
参考文献
Campbell et al.
Helvetica Chimica Acta, 1953 , vol. 36, p. 1489,1495
反应条件
1: CCl4; bromine / Irradiation.Erhitzen des Reaktionsprodukts mit Propan-1,3-diol
2: DMF; aqueous Na2S2 / Erwaermen des Reaktionsprodukts mit NaNO2 und aethanol. H2SO4
3: N2H4+H2O; KOH; propane-1,3-diol
4: Diazotization.anschliessend Behandeln mit wss. H3PO2
View Scheme
参考文献
Campbell et al.
Helvetica Chimica Acta, 1953 , vol. 36, p. 1489,1495
参考文献
Rigaudy; Tardieu
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1955 , vol. 240, p. 1347
反应条件
in neat (no solvent)
T=430°C; P=15 Torr; 1 h; Product distribution;
参考文献
Pomerantz, Martin; Combs, Gerald L.; Fink, Rina
Journal of Organic Chemistry, 1980 , vol. 45, # 1 p. 143 - 149
反应条件
1: LiAlH4
2: oxalic acid / 150 - 200 °C
View Scheme
参考文献
Rigaudy; Tardieu
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1955 , vol. 240, p. 1347
反应条件
1: LiBH4; THF
2: oxalic acid / 150 - 200 °C
View Scheme
参考文献
Rigaudy; Tardieu
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1955 , vol. 240, p. 1347
反应条件
water in acetonitrile
Irradiationin different solvent systems (MeOH, EtOH, 2-PrOH, HCONH2) and in acidic and basic solution (H2SO4-EtOH, NaOH-EtOH); Quantum yieldMechanism;
参考文献
Budac, David; Wan, Peter
Journal of Organic Chemistry, 1992 , vol. 57, # 3 p. 887 - 894
