2-戊基-2-环戊烯-1-酮合成路线 （共 119 条）
反应条件
1: 1.) LiNEt2 / 1.) HMPT, benzene, THF, -10 deg C, 1.5 h, 2.) room temp., 2 h 2: 1.) O3, 2.) H2 / 2.) Lindlar catalyst / 1.) EtOAc, -60 deg C, 2.) 1 atm 3: 89 percent / 1percent aq. NaOH / diethyl ether / 72 h / Ambient temperature View Scheme
参考文献
Synthesis, , # 8 p. 603 - 607
反应条件
1: 1.) O3, 2.) H2 / 2.) Lindlar catalyst / 1.) EtOAc, -60 deg C, 2.) 1 atm 2: 89 percent / 1percent aq. NaOH / diethyl ether / 72 h / Ambient temperature View Scheme
参考文献
Synthesis, , # 8 p. 603 - 607
反应条件
1: 84 percent / RhCl(PPh3)3 / ethanol / 110 °C 2: 91 percent / 30percent H2SO4 / 1 h / 50 °C 3: 0.53 percent / water, NaOH / dioxane / 0.17 h / Heating View Scheme
参考文献
Tetrahedron, , vol. 46, # 18 p. 6399 - 6412
反应条件
1: NaIO4 / methanol; H2O / 5 h / 60 °C 2: 40 percent / t-BuOK / CCl4; 2-methyl-propan-2-ol / 50 °C 3: p-TsOH*pyridine / acetone; H2O / Heating View Scheme
参考文献
Chemistry Letters, , p. 833 - 836
反应条件
1: p-TsOH / benzene / 5 h / Heating 2: NaIO4 / methanol; H2O / 5 h / 60 °C 3: 40 percent / t-BuOK / CCl4; 2-methyl-propan-2-ol / 50 °C 4: p-TsOH*pyridine / acetone; H2O / Heating View Scheme
参考文献
Chemistry Letters, , p. 833 - 836
反应条件
dicobalt octacarbonyl in toluene T=150°C; P=232519 - 270022 Torr; 16 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Angewandte Chemie, , vol. 102, # 12 p. 1441 - 1443
反应条件
iron(III) chloride in ethanol; water Heating;
参考文献
Cardinale, G.; Laan, J. A. M.; Russel, S. W.; Ward, J. P.
Recueil: Journal of the Royal Netherlands Chemical Society, 1982 , vol. 101, # 6 p. 199 - 202
反应条件
1: 60 percent / oxalyl chloride / benzene / Ambient temperature 2: 54 percent / AlCl3 / CH2Cl2 / 10 h / Ambient temperature View Scheme
参考文献
Tetrahedron, , vol. 47, # 38 p. 8111 - 8118
反应条件
2: aq. HCl / butan-1-ol View Scheme
参考文献
Synthetic Communications, , vol. 4, p. 303 - 306
反应条件
para-nitroperbenzoic acid in dichloromethane
参考文献
Synthesis, , p. 755 - 757
