三(三苯基膦)羰基二氢钌(II)合成路线 （共 44 条）
反应条件
triphenylphosphine in 2-methoxy-ethanol A soln. of reagents was heated under reflux for 20 min, cooled in an ice-bath;; ppt. was filtered, wshed with EtOH, H2O, EtOH again, dissolved in CH2Cl2, evapd.;;
参考文献
Boniface, Suzanne M.; Clark, George R.; Collins, Terrence J.; Roper, Warren R.
Journal of Organometallic Chemistry, 1981 , vol. 206, # 1 p. 109 - 117
反应条件
KOH in ethanol soln. of KOH in EtOH added to refluxing suspn. of Ru complex and indenein EtOH under N2, refluxed for 4 h; cooled, filtered, extd. (CH2Cl2), filtered, added MeOH, ppt. filtered after 30 min, washed with MeOH, Et2O, dried in vac.; purified by extn. (acetone), evapd., recrystd. (CH2Cl2/Et2O); elem. anal.;
参考文献
Oro, Luis A.; Ciriano, Miguel A.; Campo, Marina; Foces-Foces, Concepcion; Cano, Felix H.
Journal of Organometallic Chemistry, 1985 , vol. 289, p. 117 - 132
反应条件
in neat (no solvent) byproducts: CH4, H2; heating in vac. at 100°C for 4 h; filtration, washing with Et2O, drying in vac.;
参考文献
Yamamoto, Takakazu; Miyashita, Satoshi; Naito, Yoshiyuki; Komiya, Sanshiro; Ito, Takashi; Yamamoto, Akio
Organometallics, 1982 , vol. 1, p. 808 - 812
反应条件
ethanol in ethanol byproducts: CH4, H2; stirred at room temp. for 7 days; evapd.; IR, (1)H NMR, (31)P NMR;
参考文献
Sluys, Lori Stepan Van Der; Kubas, Gregory J.; Caulton, Kenneth G.
Organometallics, 1991 , vol. 10, p. 1033 - 1038
反应条件
in methanol Ar-atmosphere; refluxing for 45 min; cooling, filtration, evapn., extn. (Et2O), addn. of hexane, concn., crystn. on standing, collection (filtration), washing (pentane), drying (vac.); elem. anal.;
参考文献
Ayllon, Jose A.; Sayers, Stephen F.; Sabo-Etienne, Sylviane; Donnadieu, Bruno; Chaudret, Bruno; Clot, Eric
Organometallics, 1999 , vol. 18, # 20 p. 3981 - 3990
参考文献
Journal of the American Chemical Society, , vol. 128, # 42 p. 13702 - 13703
反应条件
in neat (no solvent) byproducts: PhOH, nonene; heating in vac. at 95°C for 3 h;
参考文献
Yamamoto, Takakazu; Miyashita, Satoshi; Naito, Yoshiyuki; Komiya, Sanshiro; Ito, Takashi; Yamamoto, Akio
Organometallics, 1982 , vol. 1, p. 808 - 812
反应条件
triphenylphosphine in benzene byproducts: 1-butene, 2-butene; silyl ether added to Ru complex and PPh3 in benzene, stirred at 80°C under vac. for 72 h; volatiles sepd. by trap to trap distn., anlyzed by gas chromy.; solid recrystd., analyzed by IR;
参考文献
Organometallics, , vol. 4, p. 1504 - 1508
反应条件
ethanol in benzene-d6 byproducts: RuH2(P(C6H5)3)4, CH4, H2; heated for 24 h at 60°C; evapd.; (1)H NMR, (31)P NMR;
参考文献
Organometallics, , vol. 10, p. 1033 - 1038
反应条件
hydrogen in ethanol; benzene (H2 as protect. gas); dropwise addn. of ethanolic NaBH4 soln. to benzene/ethanol soln. of Ru complex over 30 min; H2 bubbled through soln. for ca. 2 h; ppt. removed, filtrate stored 2 weeks under pentane: small red needles of (PPh3)2HRu(μ-H)3Ru(PPh3)3 and less dense white RuH2(CO)(PPh3)3 formed; soln. + CO complex decanted, Ru2 complex washed with EtOH, stored under Ar;
参考文献
Organometallics, , vol. 10, p. 1033 - 1038
