antimony pentachloride in not given fluorination of PSCl3 with SbF3; addn. of SBF3 at 70-80 °C; ratio of products depending on pressure and temp.;; fractional distn., cooling agent liquid air or CO2-acetone;;
in neat (no solvent) react. at 80-100 °C or 70-80 °C; formation of a mixt. of PSFCl2 and PSF2Cl;;
参考文献
Delwaulle, M.-L.; Francois, F.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1947 , vol. 225, p. 1308 - 1309
Full Text Show Details
Gmelin Handbook: P: MVol.C, 263, page 602 - 605
