1,3-二氢-2-苯并噻吩 2,2-二氧化物合成路线 （共 27 条）
参考文献
Cava; Deana
Journal of the American Chemical Society, 1959 , vol. 81, p. 4266
反应条件
1: 75 percent / various solvent(s) / 18 h / Heating
2: 12 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; dioxane / 48 h / Heating
View Scheme
参考文献
Brito, Cristela M.; Pinto, Diana C. G. A.; Silva, Artur M. S.; Silva, Ana M. G.; Tome, Augusto C.; Cavaleiro, Jose A. S.
European Journal of Organic Chemistry, 2006 , # 11 p. 2558 - 2569
反应条件
1: 81.2 percent / nitric acid; acetic acid; Ac2O / 5 h / 10 °C
2: 81.4 percent / tin; hydrochloric acid / ethanol / 8 h / Heating
View Scheme
参考文献
Tashbaev
Russian Chemical Bulletin, 2005 , vol. 54, # 2 p. 437 - 440
反应条件
1: 1.) BuLi / 1.) Et2O, -78 deg C -> room temperature; room temperature, 1 h, 2.) -78 deg C -> room temperature; room temperature, 2 h
2: 550 °C / 0.01 Torr
View Scheme
参考文献
Durst, Tony; Lancaster, Michael; Smith, David J. H.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1846 - 1848
反应条件
1: 40.5 percent / various solvent(s) / 14 h / 200 °C
2: 70 percent / H2 / 10percent Pd/C / various solvent(s) / 18 h / 240 °C
View Scheme
参考文献
Akula, Murthy R.; Levy, Louis A.
Synthetic Communications, 1989 , vol. 19, # 15 p. 2765 - 2772
反应条件
1: 87 percent / various solvent(s) / 18 h / Heating
2: 19 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; dioxane / 48 h / Heating
View Scheme
参考文献
Brito, Cristela M.; Pinto, Diana C. G. A.; Silva, Artur M. S.; Silva, Ana M. G.; Tome, Augusto C.; Cavaleiro, Jose A. S.
European Journal of Organic Chemistry, 2006 , # 11 p. 2558 - 2569
反应条件
1: 95 percent / various solvent(s) / 18 h / Heating
2: 21 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; dioxane / 48 h / Heating
View Scheme
参考文献
Brito, Cristela M.; Pinto, Diana C. G. A.; Silva, Artur M. S.; Silva, Ana M. G.; Tome, Augusto C.; Cavaleiro, Jose A. S.
European Journal of Organic Chemistry, 2006 , # 11 p. 2558 - 2569
