十八碳-9,12-二烯酸甲酯合成路线 （共 19 条）
反应条件
T=100 - 105°C; darauffolgenden Oxydation mit alkal.Kalimpermanganat-Loesung.Hydrogenation; linolic acid methyl ester;
参考文献
Hildlitch; Vidyarthi
Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1929 , vol. 122, p. 555,562
Chem. Zentralbl., 1929 , vol. 100, # I p. 2163
反应条件
potassium hydroxide; boron trifluoride 1.) ethylene glycol, 180 deg C, 2.) RT, 30 min; Multistep reaction;
参考文献
Berdeaux; Voinot; Angioni; Juaneda; Sebedio
JAOCS, Journal of the American Oil Chemists' Society, 1998 , vol. 75, # 12 p. 1749 - 1755
反应条件
linolic acid methyl ester;
参考文献
Haworth
Journal of the Chemical Society, 1929 , p. 1460
反应条件
pyridine; dihydrogen peroxide; methyltrioxorhenium (VII) in dichloromethane T=25°C; 8 h; regioselective reaction;
参考文献
Amato, Maria E.; Ballistreri, Francesco P.; Pappalardo, Andrea; Tomaselli, Gaetano A.; Toscano, Rosa M.; Sfrazzetto, Giuseppe Trusso
Molecules, 2013 , vol. 18, # 11 p. 13754 - 13763
反应条件
formic acid; dihydrogen peroxide in hexane; water 8 h; Tween 80 surfactant; Product distribution / selectivity;
参考文献
AROMAGEN CORPORATION; SELIFONOV, Sergey
Patent: WO2007/62158 A2, 2007 ;
Location in patent: Page/Page column 19-20 ;
反应条件
formic acid; dihydrogen peroxide in hexane; water 8 h; Tween 80 surfactant; Product distribution / selectivity;
参考文献
AROMAGEN CORPORATION; SELIFONOV, Sergey
Patent: WO2007/62158 A2, 2007 ;
Location in patent: Page/Page column 19-20 ;
反应条件
sodium hydroxide; diethylene glycol T=200°C; ein nicht ganz einheitliches Praeparat entsteht;
参考文献
Nichols; Herb; Riemenschneider
Journal of the American Chemical Society, 1951 , vol. 73, p. 251
反应条件
potassium hydroxide in ethylene glycol T=180°C; 3 h;
参考文献
JAOCS, Journal of the American Oil Chemists' Society, , vol. 75, # 12 p. 1749 - 1755
反应条件
potassium hydroxide in ethylene glycol T=180°C; 3 h; var. reaction time; Product distribution;
参考文献
JAOCS, Journal of the American Oil Chemists' Society, , vol. 75, # 12 p. 1749 - 1755
反应条件
T=100 - 105°C; darauffolgenden Oxydation mit alkal.Kalimpermanganat-Loesung.Hydrogenation; linolic acid methyl ester;
参考文献
Hildlitch; Vidyarthi
Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1929 , vol. 122, p. 555,562
Chem. Zentralbl., 1929 , vol. 100, # I p. 2163
