1,2,4-苯三羧酸三甲酯合成路线 （共 45 条）
反应条件
1: sulfuric acid / 16 h / Reflux 2: hydroquinone / m-xylene / 72 h / Inert atmosphere; Reflux 3: oxygen / platinum on carbon / m-xylene / 96 h / Reflux View Scheme
反应条件
1: hydroquinone / m-xylene / 72 h / Inert atmosphere; Reflux 2: oxygen / platinum on carbon / m-xylene / 96 h / Reflux View Scheme
反应条件
1: iodine / acetonitrile / 25 h / Reflux; Ambient light 2: hydroquinone / m-xylene / 72 h / Inert atmosphere; Reflux 3: oxygen / platinum on carbon / m-xylene / 96 h / Reflux View Scheme
反应条件
1: iodine / acetonitrile / 15 h / Reflux; Ambient light 2: hydroquinone / m-xylene / 72 h / Inert atmosphere; Reflux 3: oxygen / platinum on carbon / m-xylene / 96 h / Reflux View Scheme
参考文献
Ziegler, Thomas; Layh, Marcus; Effenberger, Franz
Chemische Berichte, 1987 , vol. 120, p. 1347 - 1356
反应条件
dicobalt octacarbonyl in methanol T=65°C; 65 h; P(CO): 2 kg/cm-2;
参考文献
Kazimura, Tsugunori; Kudo, Kiyoshi; Mori, Sadayuki; Sugita, Nobuyuki
Chemistry Letters, 1986 , p. 851 - 854
反应条件
dicobalt octacarbonyl in methanol T=65°C; 45 h; P(CO): 2 kg/cm-2;
参考文献
Kazimura, Tsugunori; Kudo, Kiyoshi; Mori, Sadayuki; Sugita, Nobuyuki
Chemistry Letters, 1986 , p. 851 - 854
参考文献
Ziegler, Thomas; Layh, Marcus; Effenberger, Franz
Chemische Berichte, 1987 , vol. 120, p. 1347 - 1356
反应条件
dicobalt octacarbonyl in methanol T=65°C; 70 h; P(CO): 2 kg/cm-2;
参考文献
Kazimura, Tsugunori; Kudo, Kiyoshi; Mori, Sadayuki; Sugita, Nobuyuki
Chemistry Letters, 1986 , p. 851 - 854
反应条件
1: methanol; 1,2,4-benzenetricarboxylic anhydride With 1,8-diazabicyclo[5.4.0]undec-7-ene T=20°C; 0.166667 h; 2: methyl iodide With 1,8-diazabicyclo[5.4.0]undec-7-ene T=20°C; chemoselective reaction;
参考文献
Jana, Amit Kumar; Karmakar, Raju; Dinda, Bidyut Kumar; Mitra, Prithiba; Ghosh, Ketaki; Karmakar, Rajdip; Mal, Dipakranjan
Journal of the Indian Chemical Society, 2012 , vol. 89, # 7 p. 975 - 979
