palladium diacetate; acetic acid in toluene T=20°C; 8 h; Inert atmosphere;

manganese(IV) oxide; palladium diacetate; p-benozquinone in toluene T=50°C; 15 h; Inert atmosphere;

palladium diacetate; acetic acid; p-benozquinone in toluene T=80°C; 20 h; Inert atmosphere;

potassium hydroxide; hydrazine hydrate; diethylene glycol

1: 65 percent / N-iodosuccinimide / acetonitrile / 0.75 h / -10 °C 2: 61 percent / Pd/C / benzene / 20 h / Heating View Scheme

1: phosphoryl chloride; 1,2-dichloro-benzene 2: hydrazine hydrate; potassium hydroxide; diethylene glycol View Scheme

alkaline solution; acetone

Cu(I)[(CH3CN)4]BF4; 2,9-dimethyl-1,10-phenanthroline; iodine; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; methyloxirane in tetrahydrofuran T=20°C; 20 h; Flow reactorInert atmosphereIrradiation; Catalytic behavior;

1: sodium t-butanolate; biphenyl-2-yl-di-tert-butyl-phosphane; tris-(dibenzylideneacetone)dipalladium(0) / toluene / 24 h / 100 °C / |Inert atmosphere; |Sealed tube 2: Cu(I)[(CH3CN)4]BF4; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; 2,9-dimethyl-1,10-phenanthroline; iodine; methyloxirane / tetrahydrofuran / 20 h / 20 °C / |Flow reactor; |Inert atmosphere; |Irradiation View Scheme

T=900°C; P=0.001 Torr; 1.83333 h; inlet temp.: 130 - 150 deg C;