反应条件
1.1: DIBAH / diethyl ether; hexane / 4 h / -78 °C 2.1: 76 percent / CH2Cl2 / 2.5 h / 20 °C 3.1: AIBN / benzene / 4 h / Heating 4.1: H2; (+/-)-10-camphorsulfonic acid / Pd(OH)2/C / methanol / 19.5 h / 20 °C 5.1: 239 mg / Et3N / CH2Cl2 / 5 h / 20 °C 6.1: 99 percent / mCPBA / CH2Cl2 / 4.5 h / 0 °C 7.1: 76 percent / AcONa / various solvent(s) / 3 h / Heating 8.1: 9-BBN / tetrahydrofuran; hexane / 8 h / 20 °C 8.2: 55 percent / H2O2; NaOH / tetrahydrofuran; hexane; H2O / 16 h / 20 °C 9.1: NaIO4; RuO2*H2O / H2O; acetone / 7 h / 20 °C View Scheme
参考文献
Miyata, Okiko; Muroya, Kanami; Kobayashi, Tomoko; Yamanaka, Rina; Kajisa, Seiko; Koide, Junko; Naito, Takeaki
Tetrahedron, 2002 , vol. 58, # 22 p. 4459 - 4479
