[rhodium(I)(carbonyl)2(acetylacetonate)]; (Ru2(η5-C5Ph4O)2(H)2(CO)4); carbon monoxide; C70H72O2P2; hydrogen in 1,4-dioxane T=120°C; P=3750.38 Torr; 36 h; Inert atmosphereAutoclave;

sodium tetrahydroborate in methanol; toluene 4 h; Ambient temperature;

1: pyridine / CH2Cl2 2: 19 percent / CH3COOK / 6 h / 120 °C 3: 93 percent / 1 N KOH / ethanol / 24 h / Ambient temperature 4: 78 percent / borontrifluoride / 0.33 h / 80 °C 5: Na2Cr2O7*2H2O, conc. AcOH, conc. H2SO4 / H2O / 2 h / Ambient temperature 6: 37 percent / NaBH4 / toluene; methanol / 4 h / Ambient temperature View Scheme

1: Na2Cr2O7*2H2O, conc. AcOH, conc. H2SO4 / H2O / 2 h / Ambient temperature 2: 37 percent / NaBH4 / toluene; methanol / 4 h / Ambient temperature View Scheme

1: 19 percent / CH3COOK / 6 h / 120 °C 2: 93 percent / 1 N KOH / ethanol / 24 h / Ambient temperature 3: 78 percent / borontrifluoride / 0.33 h / 80 °C 4: Na2Cr2O7*2H2O, conc. AcOH, conc. H2SO4 / H2O / 2 h / Ambient temperature 5: 37 percent / NaBH4 / toluene; methanol / 4 h / Ambient temperature View Scheme

1: acetone; sodium iodide 2: pentan-2-one; potassium carbonate / Behandeln des Reaktionsprodukts mit wss.-aethanol. Kalilauge 3: sulfuric acid 4: Raney nickel; methanol / 150 °C / 110326 Torr / Hydrogenation.anschliessendes Hydrolyse View Scheme

1: sulfuric acid 2: Raney nickel; methanol / 150 °C / 110326 Torr / Hydrogenation.anschliessendes Hydrolyse View Scheme

暂无反应条件数据

(i) (enzymatic oxidation), (ii) /BRN= 1098229/; Multistep reaction;

potassium hydroxide in methanol T=80°C; 5 h; Yield given;