2-甲砜基-5-苯基-1,3,4-二唑合成路线 （共 8 条）
反应条件
(NH4)6[Mo7O24]*4H2O; dihydrogen peroxide in ethanol T=0 - 20°C; 2 h; Inert atmosphere;
参考文献
Toda, Narihiro; Asano, Shigehiro; Barbas, Carlos F.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 48 p. 12592 - 12596
Angew. Chem., 2013 , vol. 125, # 48 p. 12824 - 12828,5
反应条件
1: aq. NaOH / 6 h / 20 °C 2: aq. KMnO4; glacial acetic acid / 6 h View Scheme
参考文献
Madhavan,R.; Srinivasan,V.R.
Indian Journal of Chemistry, 1969 , vol. 7, p. 760 - 765
反应条件
1: hydrazine hydrate / methanol 2: potassium hydroxide / ethanol / |Reflux 3: sodium hydroxide 4: potassium permanganate / acetic acid / 0.25 h / 20 °C View Scheme
参考文献
Li, Pei; Yin, Juan; Xu, Weiming; Wu, Jian; He, Ming; Hu, Deyu; Yang, Song; Song, Baoan
Chemical Biology and Drug Design, 2013 , vol. 82, # 5 p. 546 - 556
反应条件
1: sulfuric acid 2: hydrazine hydrate / methanol 3: potassium hydroxide / ethanol / |Reflux 4: sodium hydroxide 5: potassium permanganate / acetic acid / 0.25 h / 20 °C View Scheme
参考文献
Li, Pei; Yin, Juan; Xu, Weiming; Wu, Jian; He, Ming; Hu, Deyu; Yang, Song; Song, Baoan
Chemical Biology and Drug Design, 2013 , vol. 82, # 5 p. 546 - 556
反应条件
1: potassium hydroxide / ethanol / |Reflux 2: sodium hydroxide 3: potassium permanganate / acetic acid / 0.25 h / 20 °C View Scheme
参考文献
Li, Pei; Yin, Juan; Xu, Weiming; Wu, Jian; He, Ming; Hu, Deyu; Yang, Song; Song, Baoan
Chemical Biology and Drug Design, 2013 , vol. 82, # 5 p. 546 - 556
反应条件
1: aq. NaOH solution / anschliessend Behandeln mit einer Loesung von Methyljodid in Aethanol 2: H3PO4; P2O5 3: KMnO4; aqueous acetic acid View Scheme
参考文献
Hoggarth
Journal of the Chemical Society, 1949 , p. 1918,1922
反应条件
1: H3PO4; P2O5 2: KMnO4; aqueous acetic acid View Scheme
参考文献
Hoggarth
Journal of the Chemical Society, 1949 , p. 1918,1922
反应条件
hydrazine hydrate in 1,4-dioxane; diethyl ether 4.5 h; cooling;
参考文献
Qiu, Zao-Zao; Dai, Chao-Feng; Chao, Shu-Jun; Xu, Peng-Fei; Zhang, Zi-Yi
Journal of the Chinese Chemical Society, 2004 , vol. 51, # 6 p. 1343 - 1346
