4,4,4,-三氟丁-2-酮合成路线 （共 15 条）
反应条件
sulfuric acid in Solkane® 365mfc T=38 - 41°C; 1 h; Reflux;
参考文献
CENTRAL GLASS CO., LTD.
Patent: US2009/227821 A1, 2009 ;
Location in patent: Page/Page column 9 ;
反应条件
sulfuric acid; water T=2 - 86°C; 16 h; Product distribution / selectivity;
参考文献
CENTRAL GLASS CO., LTD.
Patent: US2009/227821 A1, 2009 ;
Location in patent: Page/Page column 9 ;
反应条件
sulfuric acid T=38 - 41°C; 1 h; Heating / reflux; Product distribution / selectivity;
参考文献
CENTRAL GLASS CO., LTD.
Patent: WO2006/43946 A1, 2006 ;
Location in patent: Page/Page column 33 ;
反应条件
sodium hydroxide in water; acetone T=25°C; 24 h; electrolyses (Pt-electrodes); Yield given;
参考文献
Journal of Organic Chemistry, , vol. 48, # 8 p. 1370
反应条件
tert.-butylhydroperoxide; copper(II) bis(trifluoromethanesulfonate) in water; acetonitrile Ambient temperature;
参考文献
Langlois, Bernard R.; Laurent, Eliane; Roidot, Nathalie
Tetrahedron Letters, 1992 , vol. 33, # 10 p. 1291 - 1294
反应条件
sulfuric acid; water T=-78 - 72°C; 17 h; Product distribution / selectivity;
参考文献
WO2006/43946 A1, ;
Page/Page column 33-34 ;
反应条件
copper(II)gluconate in tetrachloromethane; water T=80°C; 12 h;
参考文献
He, Zhengbiao; Zhang, Rui; Hu, Mingyou; Li, Lingchun; Ni, Chuanfa; Hu, Jinbo
Chemical Science, 2013 , vol. 4, # 9 p. 3478 - 3483
反应条件
potassium hydroxide in acetone electrolysis;
参考文献
Vol'pin, I. M.; Kurykin, M. A.; Grinberg, V. A.; Vasil'ev, Yu. B.; German, L. S.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 7 p. 1395 - 1400
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 7 p. 1578 - 1584
反应条件
SbF5 in liquid sulphur dioxide
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 23, # 4 p. 913 - 915
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , vol. 23, # 4 p. 942 - 945
反应条件
2,2'-azo-bisisobutyronitrile T=80 - 90°C; 1 - 3 h;
参考文献
US2004/147789 A1, ;
Page 10-11 ;
