3,6,6-三甲基-2-环己烯-1-酮合成路线 （共 32 条）
反应条件
T=400°C; 20 h; other gem-dimethyl-2-cyclohexanones, other products; MechanismProduct distribution;
参考文献
Canadian Journal of Chemistry, , vol. 62, p. 1903 - 1907
反应条件
T=400°C; 20 h; other gem-dimethyl-2-cyclohexanones, other products; MechanismProduct distribution;
参考文献
Canadian Journal of Chemistry, , vol. 62, p. 1903 - 1907
反应条件
T=400°C; 20 h; other gem-dimethyl-2-cyclohexanones, other products; MechanismProduct distribution;
参考文献
Canadian Journal of Chemistry, , vol. 62, p. 1903 - 1907
反应条件
T=400°C; 20 h; other gem-dimethyl-2-cyclohexanones, other products; MechanismProduct distribution;
参考文献
Canadian Journal of Chemistry, , vol. 62, p. 1903 - 1907
反应条件
2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; CuCl2·2H2O in acetonitrile
T=20°C; 6 h; Molecular sieve; chemoselective reaction;
参考文献
Vatele, Jean-Michel
Synlett, 2009 , # 13 p. 2143 - 2145
反应条件
ethylaluminum dichloride in toluene
T=0°C; Cyclization; 3 h;
参考文献
Imamura, Ken-Ichiro; Yoshikawa, Eiji; Gevorgyan, Vladimir; Sudo, Tomoko; Asao, Naoki; Yamamoto, Yoshinori
Canadian Journal of Chemistry, 2001 , vol. 79, # 11 p. 1624 - 1631
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene
2 h; Heating;
参考文献
De Boeck, Benoit; Herbert, Nicola M. A.; Harrington-Frost, Nicole M.; Pattenden, Gerald
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 2 p. 328 - 339
反应条件
silica gel in diethyl ether; Petroleum ether
Yield given;
参考文献
Marino,J.P.; Jaen,J.C.
Journal of the American Chemical Society, 1982 , vol. 104, p. 3165
反应条件
1: 60 percent / 1.) LDA / tetrahydrofuran; hexane / 1.) -78 deg C, 30 min, 2.) -78 deg C - room temperature, 4 h
2: 100 percent / diethyl ether / 5 h / -78 deg C - room temperature
3: silica gel / petroleum ether; diethyl ether
View Scheme
参考文献
Marino,J.P.; Jaen,J.C.
Journal of the American Chemical Society, 1982 , vol. 104, p. 3165
反应条件
1: 100 percent / diethyl ether / 5 h / -78 deg C - room temperature
2: silica gel / petroleum ether; diethyl ether
View Scheme
参考文献
Marino,J.P.; Jaen,J.C.
Journal of the American Chemical Society, 1982 , vol. 104, p. 3165
