methyl-magnesium iodide in not given GeF2 was added with stirring to (Ph3Ge)2Hg, 6h of stirring, BrCH2CH2Br was added, then MeMgI; products were not sepd.; analyzed by cpv;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Cazes, A.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981 , vol. 11, p. 443 - 454
methyl-magnesium iodide in benzene
to PhGeCl in C6H6 (Ph3Ge)2Hg was added, 12 h at 20°C with stirring, BrCH2CH2Br was added, then MeMgI in ether; hydrolysis, extraction with ether, drying , products were not sepd.; analyzed by cpv;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Cazes, A.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981 , vol. 11, p. 443 - 454
methyl-magnesium iodide in not given
GeF2 was added with stirring to (Ph3Ge)2Hg, 6h of stirring, BrCH2CH2Br was added, then MeMgI; products were not sepd.; analyzed by cpv;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Cazes, A.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981 , vol. 11, p. 443 - 454
methyl-magnesium iodide in benzene
to PhGeCl in C6H6 (Ph3Ge)2Hg was added, 2 h at 120°C, BrCH2CH2Brwas added, then CH3MgI; products were not sept; analyzed by cpv;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Cazes, A.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981 , vol. 11, p. 443 - 454
methyl-magnesium iodide in tetrahydrofuran
GeF2 and (Ph3Ge)2Hg in THF, stirring for 12 h at ambient temp., treatingof mixt. with MeMgI; mixt. was hydrolysed, extracted, dried, products were not sepd.; analyzed by cpv;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Cazes, A.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981 , vol. 11, p. 443 - 454
