1: With [CpFe(CO)2(PCy3)][BF4]; phenyl silane T=100°C; 48 h; IrradiationNeat (no solvent)Inert atmosphere; 2: With hydrogenchloride; water in tetrahydrofuran T=20°C; 1 h;
参考文献
Bezier, David; Venkanna, Gopaladasu T.; Castro, Luis C. Misal; Zheng, Jianxia; Roisnel, Thierry; Sortais, Jean-Baptiste; Darcel, Christophe
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 10 p. 1879 - 1884
1.1: n-butyllithium / tetrahydrofuran; hexane / 1.5 h / -78 °C / |Inert atmosphere 1.2: 1.17 h / -78 - 20 °C / |Inert atmosphere 2.1: tetrahydrofuran / 6 h / 60 °C / |Inert atmosphere; |Flow reactor 3.1: n-butyllithium; trifluoroacetic anhydride; triethylamine / tetrahydrofuran; hexane / 1.33 h / -50 - 100 °C / |Inert atmosphere; |Flow reactor View Scheme
参考文献
Murray, Philip R. D.; Browne, Duncan L.; Pastre, Julio C.; Butters, Chris; Guthrie, Duncan; Ley, Steven V.
Organic Process Research and Development, 2013 , vol. 17, # 9 p. 1192 - 1208
1.1: n-butyllithium / tetrahydrofuran; hexane / 1.5 h / -78 °C / |Inert atmosphere 1.2: 1.17 h / -78 - 20 °C / |Inert atmosphere 2.1: tetrahydrofuran / 6 h / 60 °C / |Inert atmosphere; |Flow reactor 3.1: n-butyllithium; trifluoroacetic anhydride; triethylamine / tetrahydrofuran; hexane / 1.33 h / -50 - 100 °C / |Inert atmosphere; |Flow reactor View Scheme
参考文献
Murray, Philip R. D.; Browne, Duncan L.; Pastre, Julio C.; Butters, Chris; Guthrie, Duncan; Ley, Steven V.
Organic Process Research and Development, 2013 , vol. 17, # 9 p. 1192 - 1208
