2-溴-5-甲氧基苯甲酸合成路线 （共 95 条）
反应条件
bromine in acetic acid
参考文献
Hellwinkel, Dieter; Bohnet, Siegbert
Chemische Berichte, 1987 , vol. 120, p. 1151 - 1174
反应条件
1: With [bis(acetoxy)iodo]benzene; iodine in 1,2-dichloro-ethane T=20°C; 1 h; 2: 3-methoxy-benzoic acid With tetrabutylammomium bromide; palladium diacetate in 1,2-dichloro-ethane T=100°C; 24 h;
参考文献
Mei, Tian-Sheng; Giri, Ramesh; Maugel, Nathan; Yu, Jin-Quan
Angewandte Chemie - International Edition, 2008 , vol. 47, # 28 p. 5215 - 5219
反应条件
2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium chlorite in acetonitrile T=35°C; pH 6.7;
参考文献
Zhao; Li; Mano; Song; Tschaen; Grabowski; Reider
Journal of Organic Chemistry, 1999 , vol. 64, # 7 p. 2564 - 2566
反应条件
hydrogenchloride pH=1;
参考文献
Nguyen, Thi-Huu; Chau, Nguyet Trang Thanh; Castanet, Anne-Sophie; Nguyen, Kim Phi Phung; Mortier, Jacques
Organic Letters, 2005 , vol. 7, # 12 p. 2445 - 2448
反应条件
1.1: s-BuLi; TMEDA / tetrahydrofuran / 2 h / -78 - -30 °C 1.2: dibromotetrachloroethane / tetrahydrofuran / 0.5 h / -30 °C 1.3: 66 percent / aq. HCl / 20 °C / pH 2 2.1: 63 percent / aq. HCl / pH 1 View Scheme
参考文献
Organic Letters, , vol. 7, # 12 p. 2445 - 2448
反应条件
potassium hydroxide; diethylene glycol
参考文献
Journal of the American Chemical Society, , vol. 70, p. 2314,2317
反应条件
1: aqueous ethanol; iron; aqueous hydrochloric acid 2: sodium nitrite; aqueous hydrochloric acid / Eintragen der bereiteten Diazoniumsalz-Loesung in eine aus Kupfer(I)-cyanid, Natriumcyanid und Wasser hergestellte Loesung und Erwaermen des Reaktionsgemisches 3: potassium hydroxide; diethylene glycol View Scheme
参考文献
Journal of the American Chemical Society, , vol. 70, p. 2314,2317
反应条件
1: sodium nitrite; aqueous hydrochloric acid / Eintragen der bereiteten Diazoniumsalz-Loesung in eine aus Kupfer(I)-cyanid, Natriumcyanid und Wasser hergestellte Loesung und Erwaermen des Reaktionsgemisches 2: potassium hydroxide; diethylene glycol View Scheme
参考文献
Journal of the American Chemical Society, , vol. 70, p. 2314,2317
反应条件
1: 61 percent / Br2 / CHCl3 / 0.5 h / 5 °C 2: alkaline permanganate View Scheme
参考文献
Tetrahedron, , vol. 36, # 17-K p. 2513 - 2520
反应条件
permanganate(VII) ion; acetone
参考文献
Justus Liebigs Annalen der Chemie, , vol. 391, p. 44
