(4-甲氧苯基)二甲基硅烷醇合成路线 （共 37 条）
反应条件
[{RuCl2(cymene)}2]; water in acetonitrile
参考文献
Rayment, Elizabeth J.; Summerhill, Nick; Anderson, Edward A.
Journal of Organic Chemistry, 2012 , vol. 77, # 16 p. 7052 - 7060
反应条件
1: para-iodoanisole With n-butyllithium in diethyl ether T=-78°C; Inert atmosphere; 2: cyclo-(Me2SiO)3 in diethyl ether T=-78 - 20°C; Inert atmosphere;
参考文献
Denmark, Scott E.; Smith, Russell C.; Chang, Wen-Tau T.; Muhuhi, Joseck M.
Journal of the American Chemical Society, 2009 , vol. 131, # 8 p. 3104 - 3118
反应条件
1: 1-bromo-4-methoxy-benzene With n-butyllithium in diethyl ether T=-78°C; Metallation; 1 h; 2: cyclo-(Me2SiO)3 in diethyl ether T=20°C; Substitution; 13 h;
参考文献
Hirabayashi, Kazunori; Kawashima, Jun; Nishihara, Yasushi; Mori, Atsunori; Hiyama, Tamejiro
Organic Letters, 1999 , vol. 1, # 2 p. 299 - 301
反应条件
(TBA)4[γ-SiW10O34(H2O)2]; dihydrogen peroxide in water; acetonitrile T=59.84°C; 4 h;
参考文献
Mitsudome, Takato; Noujima, Akifumi; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi
Chemical Communications, 2009 , # 35 p. 5302 - 5304
反应条件
1: With 2,2,6,6-tetramethyl-piperidine-N-oxyl; potassium bromide in acetone T=20°C; 0.166667 h; 2: With sodium hypochlorite; sodium hydrogencarbonate in water; acetone T=20°C; 1 h;
参考文献
Takeda, Daisuke; Oyama, Ryo; Yamada, Shozo
Chemistry Letters, 2009 , vol. 38, # 6 p. 532 - 533
反应条件
2-dimethylaminoethylmercaptan hydrochloride; acetic acid in acetonitrile T=20°C; 2 h;
参考文献
Denmark, Scott E.; Kallemeyn, Jeffrey M.
Organic Letters, 2003 , vol. 5, # 19 p. 3483 - 3486
反应条件
1.1: PdCl2; 2-(di-t-butylphosphino)biphenyl; i-Pr2NEt / 1-methyl-pyrrolidin-2-one / 0.5 h / 20 °C 1.2: 93 percent Chromat. / CH2Cl2 / 0.5 h / 20 °C 2.1: 0.692 g / aq. AcOH; (CH3)2NC2H4SH*HCl / acetonitrile / 2 h / 20 °C View Scheme
参考文献
Denmark, Scott E.; Kallemeyn, Jeffrey M.
Organic Letters, 2003 , vol. 5, # 19 p. 3483 - 3486
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -50 °C 1.2: 2 h / -50 - -10 °C 2.1: N,N-dimethyl-formamide / 3 h / 90 °C 3.1: potassium carbonate / methanol / 2.5 h / 20 °C 4.1: 2,2,6,6-tetramethyl-piperidine-N-oxyl; potassium bromide / acetone / 0.17 h / 20 °C 4.2: 1 h / 20 °C View Scheme
参考文献
Rayment, Elizabeth J.; Summerhill, Nick; Anderson, Edward A.
Journal of Organic Chemistry, 2012 , vol. 77, # 16 p. 7052 - 7060
反应条件
9,10-anthracenedicarbonitrile; oxygen in acetonitrile 3 h; Ambient temperatureIrradiation; Rate constantMechanism;
参考文献
Mizuno, Kazuhiko; Tamai, Toshiyuki; Hashida, Isao; Otsuji, Yoshio
Journal of Organic Chemistry, 1995 , vol. 60, # 9 p. 2935 - 2937
反应条件
bis(η3-allyl-μ-chloropalladium(II)); caesium carbonate; triphenylphosphine in toluene T=90°C; 12 h; Product distribution; Further Variations:ReagentsSolvents;
参考文献
Denmark, Scott E.; Ober, Michael H.
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1703 - 1714
