3,7-二甲基-6-辛烯酸甲酯合成路线 （共 22 条）
反应条件
1: 85 percent 2: 1. sodium methaperiodate 2. reflux, toluene, 20 h, CaCO3 View Scheme
参考文献
Fujisawa, Tamotsu; Sato, Toshio; Kawara, Tatsuo; Noda, Atsunari; Obinata,Toshiyuki
Tetrahedron Letters, 1980 , vol. 21, p. 2553 - 2554
反应条件
1: 85 percent 2: 1. sodium methaperiodate 2. reflux, toluene, 20 h, CaCO3 3: LiAlH4 View Scheme
参考文献
Fujisawa, Tamotsu; Sato, Toshio; Kawara, Tatsuo; Noda, Atsunari; Obinata,Toshiyuki
Tetrahedron Letters, 1980 , vol. 21, p. 2553 - 2554
反应条件
1: 85 percent 2: 1. sodium methaperiodate 2. reflux, toluene, 20 h, CaCO3 3: LiAlH4 View Scheme
参考文献
Fujisawa, Tamotsu; Sato, Toshio; Kawara, Tatsuo; Noda, Atsunari; Obinata,Toshiyuki
Tetrahedron Letters, 1980 , vol. 21, p. 2553 - 2554
反应条件
hydrogen; sodium methylate; homogeneous ruthenium complex in tetrahydrofuran T=100°C; P=37503.8 Torr; 2.5 h; Title compound not separated from byproducts.;
参考文献
Saudan, Lionel A.; Saudan, Christophe M.; Debieux, Catherine; Wyss, Patrick
Angewandte Chemie - International Edition, 2007 , vol. 46, # 39 p. 7473 - 7476
反应条件
ammonium formate; palladium on activated charcoal in methanol
T=25°C; 1 h;
参考文献
Ranu, Brindaban C.; Sarkar, Arunkanti
Tetrahedron Letters, 1994 , vol. 35, # 46 p. 8649 - 8650
反应条件
manganese(IV) oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-dimethyl-1H-1,2,4-triazol-4-ium iodide in dichloromethane
T=20°C; Inert atmosphere;
参考文献
Maki, Brooks E.; Chan, Audrey; Phillips, Eric M.; Scheidt, Karl A.
Tetrahedron, 2009 , vol. 65, # 16 p. 3102 - 3109
反应条件
hydrogen; platinum in ethanol
Ambient temperature;
参考文献
Odinokov, V. N.; Kukovinets, O. S.; Sakharova, N. I.; Tolstikov, G. A.
Russian Journal of Organic Chemistry, 1993 , vol. 29, # 1.1 p. 24 - 30
Zhurnal Organicheskoi Khimii, 1993 , vol. 29, # 1 p. 31 - 38
参考文献
Fujisawa, Tamotsu; Sato, Toshio; Kawara, Tatsuo; Noda, Atsunari; Obinata,Toshiyuki
Tetrahedron Letters, 1980 , vol. 21, p. 2553 - 2554
反应条件
1: 1.) LDA / 1.) THF, hexane, -75 deg C, 40 min, 2.)a) THF, hexane, -70 deg C, 1 h, b) 20 deg C, 1 h
2: 3.42 g / TsOH*Py / acetone; H2O / 2 h / Heating
3: 1.) butylithium / 1.) THF, hexane, -78 deg C, 1 h, 2.)a) THF, hexane, -78 deg C, 1 h, b) 20 deg C, 15 h
4: 82 percent / H2 / Pt-black / ethanol / Ambient temperature
View Scheme
参考文献
Odinokov, V. N.; Kukovinets, O. S.; Sakharova, N. I.; Tolstikov, G. A.
Russian Journal of Organic Chemistry, 1993 , vol. 29, # 1.1 p. 24 - 30
Zhurnal Organicheskoi Khimii, 1993 , vol. 29, # 1 p. 31 - 38
反应条件
triethylamine
3 h; Ambient temperature;
参考文献
Ohta, Shunsaku; Hayakawa, Satoshi; Okamoto, Masao
Tetrahedron Letters, 1984 , vol. 25, # 49 p. 5681 - 5684
