2,3,4,5,6-五甲基苯甲酸合成路线 (共 17 条)
反应条件
nitric acid; acetic anhydride; sodium carbonate 1.) 0 deg C, 2 h, 2.) 0 deg C to RT, overnight; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Keumi, Takashi; Morita, Toshio; Teramoto, Koichi; Takahashi, Hisakazu; Yamamoto, Hiroshi; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3439 - 3446
参考文献
Jacobsen
Chemische Berichte, 1889 , vol. 22, p. 1217
反应条件
trifluoroacetic acid 2 h; Heating;
参考文献
Keumi, Takashi; Morita, Toshio; Inui, Yoko; Teshima, Naomi; Kitajima, Hidehiko
Synthesis, 1985 , # 10 p. 979 - 980
反应条件
nitric acid; acetic anhydride; sodium carbonate 1.) 0 deg C, 2 h, 2.) 0 deg C to RT, overnight; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Keumi, Takashi; Morita, Toshio; Teramoto, Koichi; Takahashi, Hisakazu; Yamamoto, Hiroshi; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3439 - 3446
反应条件
in cyclohexane; water; cyclohexanone; acetic acid
参考文献
E. I. Du Pont de Nemours and Company
Patent: US4195040 A1, 1980 ;
反应条件
dichloro-acetic acid; oxygen in methanol; acetonitrile
T=20°C; 4 h; Irradiation;
参考文献
Santamaria, J.; Jroundi, R.; Rigaudy, J.
Tetrahedron Letters, 1989 , vol. 30, # 35 p. 4677 - 4680
反应条件
1: zinc cyanide; AlCl3
View Scheme
参考文献
Smith; Webster; Guss
Journal of the American Chemical Society, 1937 , vol. 59, p. 1078,1080
反应条件
potassium permanganate
参考文献
Smith; Rosenbaum
Journal of the American Chemical Society, 1951 , vol. 73, p. 3843,3846
反应条件
3,3-dimethyldioxirane in acetone
72 h; Ambient temperature;
参考文献
Murray, Robert W.; Singh, Megh; Rath, Nigam
Journal of Organic Chemistry, 1997 , vol. 62, # 25 p. 8794 - 8799
参考文献
Smith; Stanfield
Journal of the American Chemical Society, 1949 , vol. 71, p. 81
Full Text View citing articles Show Details
Smith; Webster; Guss
Journal of the American Chemical Society, 1937 , vol. 59, p. 1078,1080
Full Text Show Details
Clement
Bulletin de la Societe Chimique de France, 1938 , vol. <5> 5, p. 1011,1019
Annales de Chimie (Cachan, France), 1940 , vol. <11> 13, p. 243,302, 305