osmium(VIII) oxide; trimethylamine-N-oxide in pyridine; water; tert-butyl alcohol 96 h; Heating;

pyridine; osmium(VIII) oxide; trimethylamine-N-oxide; water in tert-butyl alcohol 24 h; Reflux;

lithium aluminium tetrahydride in diethyl ether

aluminum isopropoxide; isopropyl alcohol

暂无反应条件数据

in dichloromethane-d2 byproducts: (CH3)2C4H4(CH3CO)CH2COH; under N2; an equimolar mixt. of Bi-contg. compd. and (-)-pinanediol in CD2Cl2 was refluxed at room temp. for 12 h; (1)H NMR monitoring at room temp.;

in dichloromethane-d2 byproducts: (CH3)2CC6H7CH3(OH)(OC6H5), C6H6, (CH3)2C4H4COCH3CH2COH; Irradiation (UV/VIS); under N2; an equimolar mixt. of Bi-contg. compd. and (-)-pinanediol in CD2Cl2 was refluxed at room temp.; irradn. (366 nm) after 12 h; (1)H NMR monitoring at room temp.;

in benzene byproducts: propene; reflux for 1 h; distn.; elem. anal.;