1,1,1-三(二苯基膦甲基)乙烷合成路线 （共 15 条）
反应条件
in tetrahydrofuran Schlenk techniques used; protective gas: N2; detailed description given; mixture of CH3C(CH2P(C6H5)2)3 and of W(CO)3PMTA in THF; reflux (8 h);; evapn.; washing (hexane); filtration (through alumina/CH2Cl2); evapn.to dryness; recrystn. (CH2Cl2/hexane/-20°C);;
参考文献
Zanotti, Valerio; Rutar, V.; Angelici, Robert J.
Journal of Organometallic Chemistry, 1991 , vol. 414, # 2 p. 177 - 191
反应条件
in tetrahydrofuran under N2, react. at 203 K; not isolated, identified by (31)P-NMR;
参考文献
Polyhedron, , vol. 12, p. 721 - 730
反应条件
NaCl in 2-methoxy-ethanol refluxing IrCl3.3H2O and NaCl in soln. for 30 mins., cooling to room temp. and addn. of MeC(CH2PPh2)3, refluxing 16 h (olive-green soln. turned colorless, deposition of white ppt.) ; all operations under N2; cooling to room temp., collection of ppt., extn. with CH2Cl2, removal of CH2l2 in vauo;
参考文献
Geerts, Rolf L.; Huffman, John C.; Westerberg, D. Eric; Folting, Kirsten; Caulton, Kenneth G.
New Journal of Chemistry, 1988 , vol. 12, p. 455 - 466
反应条件
hydrogen T=164°C; P=36961.4 - 52476.2 Torr; 15 h; Product distribution / selectivity;
参考文献
WO2003/93208 A1, ;
Page/Page column 9 ;
反应条件
hydrogen T=164°C; P=36961.4 - 52476.2 Torr; 15 h; Product distribution / selectivity;
参考文献
WO2003/93208 A1, ;
Page/Page column 9 ;
