1,1,1-三(二苯基膦甲基)乙烷合成路线 （共 15 条）
反应条件
potassium hydroxide; potassium carbonate in dimethyl sulfoxide T=90 - 130°C;
参考文献
Muth, A.; Walter, O.; Huttner, G.; Asam, A.; Zsolnai, L.; Emmerich, Ch.
Journal of Organometallic Chemistry, 1994 , vol. 468, # 1-2 p. 149 - 164
反应条件
1: chloro-diphenylphosphine With sodium in anhydrous butyl ether T=105°C; 2 h; 2: 2,2-bis(chloromethyl)-1-chloropropane in anhydrous butyl ether T=105°C; 2 h;
参考文献
BASF Aktiengesellschaft
Patent: WO2006/84878 A1, 2006 ;
Location in patent: Page/Page column 20 ;
反应条件
in chloroform-d1 T=25°C; 36 h;
参考文献
Alajarin, Mateo; Berna, Jose; Lopez-Leonardo, Carmen; Steed, Jonathan W.
Chemical Communications, 2008 , # 20 p. 2337 - 2339
反应条件
potassium hydroxide; potassium carbonate in dimethyl sulfoxide 1.) 50 deg C, 2 h, 2.) 60 deg C, 6 h;
参考文献
Journal of Organometallic Chemistry, , vol. 468, # 1-2 p. 149 - 164
反应条件
1: 1.) 98percent KOtBu / 1.) THF, 23 deg C, 30 min, 2.) THF, 23 deg C, 14 h 2: 1.) n-BuLi / 1.) THF, hexane, 0 deg C, 30 min, 2.) THF, hexane, reflux, 3 h View Scheme
参考文献
Chemische Berichte, , vol. 127, # 10 p. 1837 - 1842
反应条件
1: 1.) n-BuLi / 1.) THF, hexane, 0 deg C, 30 min, 2.) THF, hexane, reflux, 3 h View Scheme
参考文献
Chemische Berichte, , vol. 127, # 10 p. 1837 - 1842
反应条件
1: 1.) 98percent KOtBu / 1.) THF, 23 deg C, 30 min, 2.) THF, 23 deg C, 14 h 2: 1.) n-BuLi / 1.) THF, hexane, 0 deg C, 30 min, 2.) THF, hexane, reflux, 3 h View Scheme
参考文献
Chemische Berichte, , vol. 127, # 10 p. 1837 - 1842
反应条件
Yield given. Multistep reaction;
参考文献
Chemische Berichte, , vol. 127, # 10 p. 1837 - 1842
反应条件
in toluene Ar atmosphere, heating (80°C, 10 min, 90°C, overnight), pptn.; washing of ppt. (toluene, Et2O), drying;
参考文献
Rhodes, Larry F.; Sorato, Carla; Venanzi, Luigi M.; Bachechi, Fiorella
Inorganic Chemistry, 1988 , vol. 27, p. 604 - 610
反应条件
in toluene Ar atmosphere, heating (80-90°C, 15 min);
参考文献
Rhodes, Larry F.; Sorato, Carla; Venanzi, Luigi M.; Bachechi, Fiorella
Inorganic Chemistry, 1988 , vol. 27, p. 604 - 610
