1-甲基-4-[(三氟甲基)亚磺酰]苯合成路线 （共 6 条）
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in tetrahydrofuran
30 min at -25 deg C, then slowly warmed up to 10 deg C (total time 2 h);
参考文献
Movchun, Valeria N.; Kolomeitsev, Alexander A.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 1995 , vol. 70, # 2 p. 255 - 258
反应条件
trifluoromethylsulfonic anhydride
T=20°C; Title compound not separated from byproducts;
参考文献
Wakselman; Tordeux; Freslon; Saint-Jalmes
Synlett, 2001 , # 4 p. 550 - 552
反应条件
1: SbF3
2: HNO3, H2SO4
3: SnCl2, aq. HCl / methanol
4: (i) aq. HCl, NaNO2, (ii) aq. HCl, Na2S2O3
View Scheme
参考文献
Yagupol'skii,L.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1965 , vol. 35, # 2 p. 377 - 387,377 - 385
反应条件
1: HNO3, H2SO4
2: SnCl2, aq. HCl / methanol
3: (i) aq. HCl, NaNO2, (ii) aq. HCl, Na2S2O3
View Scheme
参考文献
Yagupol'skii,L.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1965 , vol. 35, # 2 p. 377 - 387,377 - 385
反应条件
1: SnCl2, aq. HCl / methanol
2: (i) aq. HCl, NaNO2, (ii) aq. HCl, Na2S2O3
View Scheme
参考文献
Yagupol'skii,L.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1965 , vol. 35, # 2 p. 377 - 387,377 - 385
反应条件
(i) aq. HCl, NaNO2, (ii) aq. HCl, Na2S2O3; Multistep reaction;
参考文献
Yagupol'skii,L.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1965 , vol. 35, # 2 p. 377 - 387,377 - 385
