in toluene mixt. of Sb and Sn deriv. in a molar ratio 2:1 was allowed to stand in an evacuated glass ampoule at room temp. for 24 h; crystals of Ph4SbCl filtered off; filtrate evapd; residue chromd. on SiO2; identified by elem. anal.;
参考文献
Sharutin; Sharutina; Senchurin; Kovaleva; Shcherbakov; Gladyshev
Russian Journal of General Chemistry, 2000 , vol. 70, # 1 p. 64 - 65
in toluene mixt. of Sb and Sn deriv. in a molar ratio 2:1 was allowed to stand in an evacuated glass ampoule at room temp. for 24 h; crystals of Ph4SbCl filtered off; filtrate evapd; residue chromd. on SiO2; identified by elem. anal.;
参考文献
Sharutin; Sharutina; Senchurin; Kovaleva; Shcherbakov; Gladyshev
Russian Journal of General Chemistry, 2000 , vol. 70, # 1 p. 64 - 65
in toluene mixt. of SbPh5 and of SbPh3SO4 in toluene heated at 90-100°C for 6 h in glass evacuated ampoule; solvent removed; residue dissolved in hot water and soln. filtered off; solvent evapd. and (Ph4Sb)2SO4 was obtained;
HCl in ethanol; toluene mixt. of SbPh5 and of SbPh2Br3 in toluene was allowed to stand at 100°C for 1 h; solvent evapd. and Ph4SbBr recrystd. from water; residueinsol. in water dissolved in hot EtOH/HCl; after cooling Ph3SbBr2 was o btained;
参考文献
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, , vol. 29, # 2 p. 89 - 92
in toluene mixt. of Sb and Sn deriv. in a molar ratio 2:1 was allowed to stand in an evacuated glass ampoule at room temp. for 24 h; crystals of Ph4SbBr filtered off; filtrate evapd; residue chromd. on SiO2; identified by elem. anal. and NMR spectrum;
参考文献
Sharutin; Sharutina; Senchurin; Kovaleva; Shcherbakov; Gladyshev
Russian Journal of General Chemistry, 2000 , vol. 70, # 1 p. 64 - 65
