in toluene a mixt. of Sb-contg. and Hg-contg. compds. in toluene was heated at 100°C for 1 h; the crystals were filtered off, washed with petroleum ether, and dried to obtain Ph4SbCl; the solvent was removed from the filtrate and the residue was chromd. on Silicagel L 5/40 (eluent petroleum ether) to obtain Hg-contg. compd.;
参考文献
Russian Journal of General Chemistry, , vol. 73, # 8 p. 1322 - 1322
in toluene a mixt. of Sb-contg. and Hg-contg. compds. in toluene was heated at 100°C for 1 h; the react. mixt. was cooled; the residue was extd. with hot water; the ext. was evapd. to obtain Ph4SbCl; the water-insol. residue was chromd. on Silica gel L 5/40 (eluent petroleum ether) to obtain Ph2Hg; FeHg-contg. compd. insol. in petroleum ether was crystd. from toluene;
参考文献
Russian Journal of General Chemistry, , vol. 73, # 8 p. 1322 - 1322
in toluene mixt. of Sb and Sn deriv. was allowed to stand in an evacuated glass ampoule at room temp. for 24 h; crystals of Ph4SbCl filtered off; filtrate evapd; residue chromd. on SiO2; identified by elem. anal. and NMR spectrum;
参考文献
Sharutin; Sharutina; Senchurin; Kovaleva; Shcherbakov; Gladyshev
Russian Journal of General Chemistry, 2000 , vol. 70, # 1 p. 64 - 65
HCl in ethanol; toluene mixt. of SbPh5 and of SbPh2Cl3 hydrate in toluene was allowed to stand at 100°C for 1 h; solvent evapd. and Ph4SbCl recrystd. from water;residue insol. in water dissolved in hot EtOH/HCl; after cooling Ph3SbC l2 was obtained;
参考文献
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, , vol. 29, # 2 p. 89 - 92
in toluene mixt. of Sb and Sn deriv. in a molar ratio 2:1 was allowed to stand in an evacuated glass ampoule at room temp. for 24 h; crystals of Ph4SbBr filtered off; filtrate evapd; residue chromd. on SiO2; identified by elem. anal. and NMR spectrum;
参考文献
Sharutin; Sharutina; Senchurin; Kovaleva; Shcherbakov; Gladyshev
Russian Journal of General Chemistry, 2000 , vol. 70, # 1 p. 64 - 65
