1-甲氧基-1,3-环己二烯合成路线 （共 48 条）
反应条件
T=140°C; 16 h; Neat (no solvent);
参考文献
Abid, Obaid-Ur-Rahman; Nawaz, Muhammad; Ibad, Muhammad Farooq; Khera, Rasheed Ahmad; Iaroshenko, Viktor; Langer, Peter
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 7 p. 2185 - 2191
反应条件
1: benzene
2: (i) KOtBu, (ii) Ag2O
3: 120 °C
4: OH-, H2O
5: (i) Ac2O, H2SO4, (ii) /BRN= 1720992/, AgNO3, aq. (NH4)2S2O8, (iii) aq. Na2CO3
View Scheme
参考文献
Giles,R.G.F.; Roos,G.H.P.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 1632 - 1635
反应条件
1: 4-methoxy-1-vinyl-benzene; (+/-)-2-(p-tolylsulfinyl)-1,4-benzoquinone in water
T=20°C; Cycloaddition; Diels-Alder reaction; 48 h;
2: 1-methyoxy-1,3-cyclohexadiene in dichloromethane
T=-20°C; Cycloaddition; Elimination; 24 h;
参考文献
Carreno, M. Carmen; Urbano, Antonio
Tetrahedron Letters, 2000 , vol. 41, # 21 p. 4117 - 4121
反应条件
1: 80 percent / CH2Cl2 / 24 h / -20 °C
2: 75 percent / 120 °C / 8 Torr
View Scheme
参考文献
Carreno, M. Carmen; Ruano, Jose L. Garcia; Urbano, Antonio
Journal of Organic Chemistry, 1992 , vol. 57, # 25 p. 6870 - 6876
反应条件
2: aq. Na2CO3
3: (heating)
View Scheme
参考文献
Birch,A.J. et al.
Journal of the Chemical Society, 1964 , p. 2941 - 2944
反应条件
T=140°C; Diels-Alder reaction; 2 h;
参考文献
Ashburn, Bradley O.; Carter, Rich G.
Organic and Biomolecular Chemistry, 2008 , vol. 6, # 2 p. 255 - 257
反应条件
T=140°C; Diels-Alder reaction; 2 h;
参考文献
Ashburn, Bradley O.; Carter, Rich G.
Organic and Biomolecular Chemistry, 2008 , vol. 6, # 2 p. 255 - 257
反应条件
1: 96 percent / benzene / 1.5 h / Heating
2: 76 percent / cerium(IV) ammonium nitrate / acetonitrile; H2O / 0.5 h
3: 71 percent / 0.5 h / 140 °C
View Scheme
参考文献
Ameer, Farouk; Giles, Robin G. F.; Green, Ivan R.; Pearce, Rene
Synthetic Communications, 2004 , vol. 34, # 7 p. 1247 - 1258
