3-甲基-2-环己烯-1-醇合成路线 （共 78 条）
反应条件
in pentane T=25°C; 1 h; ether; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 22, # 37 p. 3663 - 3666
反应条件
phosphorous acid trimethyl ester in tetrahydrofuran 1 h; Ambient temperature; Yield given;
参考文献
Liebigs Annalen der Chemie, , # 3 p. 564 - 575
反应条件
1: 1.) LDA / 1.) THF, -40 deg C, 10 min 2.) 1h, RT, 2: trimethylphosphite / tetrahydrofuran / 1 h / Ambient temperature View Scheme
参考文献
Liebigs Annalen der Chemie, , # 3 p. 564 - 575
反应条件
1: 1.) C4H9Li / 1.) ether, 1h, -10 deg C 2: 1.) LDA / 1.) THF, -40 deg C, 10 min 2.) 1h, RT, 3: trimethylphosphite / tetrahydrofuran / 1 h / Ambient temperature View Scheme
参考文献
Liebigs Annalen der Chemie, , # 3 p. 564 - 575
反应条件
sodium tetrahydroborate in methanol Luche reduction;
参考文献
Angewandte Chemie - International Edition, , vol. 49, # 26 p. 4491 - 4494
反应条件
in tetrahydrofuran -78 deg C -> room temperature;
参考文献
Tetrahedron Letters, , vol. 31, # 11 p. 1553 - 1556
反应条件
lithium aluminium tetrahydride in diethylene glycol dimethyl ether T=0°C; 0.0833333 h; other substituted cyclohexanones; other reducing agents; other solvent; stereochemistry of the complex metal hydride reduction; Product distribution;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 69, # 11 p. 3297 - 3303
反应条件
Me2(t-BuO)2CoLi in tetrahydrofuran 18 h; -70 deg C -> room temperature; other alkyl derivatives of 3d metals; other solvents; Product distribution;
参考文献
Tetrahedron Letters, , vol. 31, # 11 p. 1553 - 1556
反应条件
oxygen; sodium sulfite 1) 60 grad C; Multistep reaction. Title compound not separated from byproducts;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 322, # 6 p. 915 - 932
反应条件
(i) LDA, THF, (ii) /BRN= 969135/, (iii) P(OMe)3, MeOH; Multistep reaction;
参考文献
Tetrahedron Letters, , p. 1385 - 1388
