3-碘-1,2,4,5-四甲基苯合成路线 （共 19 条）
反应条件
sulfuric acid; potassium 4-iodylbenzenesulfonate; iodine in water; acetonitrile T=65°C; 12 h;
参考文献
Yusubov, Mekhman S.; Yusubova, Roza Y.; Nemykin, Victor N.; Maskaev, Andrey V.; Geraskina, Margarita R.; Kirschning, Andreas; Zhdankin, Viktor V.
European Journal of Organic Chemistry, 2012 , # 30 p. 5935 - 5942,8
反应条件
hydrogenchloride; α,α,α-trifluorotoluene; dihydrogen peroxide; iodine in 2,2,2-trifluoroethanol; water T=20°C; 12 h;
参考文献
Advanced Synthesis and Catalysis, , vol. 355, # 7 p. 1243 - 1248
反应条件
iodosylbenzene; hydrogen iodide in solid 0.0833333 h; Ambient temperature;
参考文献
Chemistry Letters, , # 8 p. 1391 - 1392
反应条件
potassium iodide; Tl(OCOCF3)3 1.) trifluoroacetic acid, 30 min, 2.) H2O; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of the American Chemical Society, , vol. 102, # 21 p. 6504 - 6512
反应条件
boron trifluoride diethyl etherate; potassium iodide; Tl(OCOCF3)3 1.) trifluoroacetic acid, 0.5 min, 2.) H2O; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of the American Chemical Society, , vol. 102, # 21 p. 6504 - 6512
反应条件
boron trifluoride diethyl etherate; potassium iodide; Tl(OCOCF3)3 1.) trifluoroacetic acid, 1 h, 2.) water, 30 min; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of the American Chemical Society, , vol. 102, # 21 p. 6504 - 6512
反应条件
boron trifluoride diethyl etherate; potassium iodide; Tl(OCOCF3)3 multistep reaction, influence of time and reagents; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 102, # 21 p. 6504 - 6512
反应条件
(NH4)2S2O8; copper diacetate; iodine; trifluoroacetic acid; trifluoroacetic anhydride in acetic acid; acetonitrile 24 h; Ambient temperaturearomatic iodination: competition reaction with mesitylene: kMES/kDUR; other conc. other times; or with Et4NI, NaNO3, O2; Product distributionMechanism;
参考文献
Journal of Organic Chemistry, , vol. 56, # 10 p. 3238 - 3245
反应条件
iodine cloride; 1,3,5-trimethyl-benzene in various solvent(s) T=20°C; 0.5 h; Kinetics; Further Variations:ReagentsSolvents;
参考文献
Fabbrini, Maura; Galli, Carlo; Gentili, Patrizia; Macchitella, Daniele; Petride, Horia
Journal of the Chemical Society. Perkin Transactions 2, 2001 , # 9 p. 1516 - 1521
反应条件
ammonium cerium(IV) nitrate; iodine in acetic acid; acetonitrile 1 h; Ambient temperaturearomatic iodination: competition reaction with mesitylene: kMES/kDUR; other conc., other solvents, other reaction time; Product distributionMechanism;
参考文献
Journal of Organic Chemistry, , vol. 56, # 10 p. 3238 - 3245
