3-异丙烯基-α,α-二甲基苄基异氰酸酯合成路线 （共 5 条）
反应条件
ammonium tosylate in toluene
参考文献
Journal of Organic Chemistry, , vol. 29, p. 143 - 145
反应条件
1.1: ozone; oxygen / dichloromethane / -78 °C
1.2: 10 h / 20 °C
2.1: water; hydrogenchloride / |Reflux; |Inert atmosphere
3.1: chlorosulfonic acid / chloroform / 0.42 h / 0 °C / |Inert atmosphere
4.1: KNO2 / |Inert atmosphere
4.2: 3407 / 2 h / pH 2.8 / |Inert atmosphere
View Scheme
参考文献
BRANDEIS UNIVERSITY; THE BRIGHAM AND WOMEN'S HOSPITAL, INC.; HEDSTROM, Lizbeth, K.; CUNY, Gregory, D.; GORLA, Suresh, Kumar; KAVITHA, Mandapati
Patent: WO2014/28931 A2, 2014 ;
反应条件
dibutyl tin dilaurate
T=40 - 60°C; 4 h;
参考文献
Henkel Ireland Limited
Patent: US8053589 B1, 2011 ;
Location in patent: Page/Page column 17 ;
反应条件
tetraethylammonium cyanide; water in ethylene glycol dimethyl ether
参考文献
Hoover,F.W.; Rothrock,H.S.
Journal of Organic Chemistry, 1964 , vol. 29, p. 143 - 145
