2-苯基-1,2-环氧丙烷合成路线 (共 116 条)
反应条件
1,2,3,4,5,6-hexachlorocyclo-hexane in benzene T=45°C; 2 h; Further byproducts given;
参考文献
Journal of Organic Chemistry, , vol. 62, # 12 p. 3849 - 3857
反应条件
tert.-butylhydroperoxide in water; N,N-dimethyl-formamide T=90°C; 5 h;
参考文献
Journal of Molecular Catalysis A: Chemical, , vol. 334, # 1-2 p. 44 - 51
反应条件
sodium hydroxide T=120°C;
反应条件
TPP; oxygen; DAF in benzene T=20°C; 0.5 h; IrradiationO-transfer reaction; trapping of carbonyl oxide from 9-diazofluorene; further temperatures; relative reactivity with various types peroxides (perbenzoic acid, 25 deg C); Product distributionMechanism;
参考文献
Journal of the American Chemical Society, , vol. 103, # 13 p. 3832 - 3837
反应条件
dihydrogen peroxide in water; acetonitrile T=50°C; 2 h;
参考文献
Journal of Materials Chemistry, , vol. 21, # 9 p. 2997 - 3005
反应条件
potassium hydroxide in tert-butyl alcohol T=40 - 50°C; Corey-Chaykovsky epoxidation; 12 h;
参考文献
Letters in Organic Chemistry, , vol. 8, # 7 p. 509 - 514
反应条件
sodium hydride in tetrahydrofuran; dimethyl sulfoxide T=0°C;
参考文献
Tetrahedron Letters, , vol. 55, # 6 p. 1243 - 1246
反应条件
in dichloromethane T=-20°C;
参考文献
Angewandte Chemie, , vol. 103, # 10 p. 1395 - 1396
反应条件
hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III); 3-chloro-benzenecarboperoxoic acid in dichloromethane T=-78°C; 3 h; competitive epoxidation in the presence of var. iron porphyrins; other alkenes, other oxidants, other catalyst, other solvents;
参考文献
Journal of the American Chemical Society, , vol. 117, # 25 p. 6691 - 6697
反应条件
1,4-dimethoxy-2,3-dimethylbenzene; oxygen in acetonitrile T=0°C; 6 h; Irradiation; Product distributionQuantum yield; Further Variations:Reagentsirradiation time;
参考文献
Tetrahedron Letters, , vol. 42, # 13 p. 2505 - 2508