2-苯基-1,2-环氧丙烷合成路线 (共 116 条)
反应条件
dihydrogen peroxide; benzoic acid in dichloromethane; water T=0°C; 0.116667 h;
参考文献
Anelli, Pier Lucio; Banfi, Stefano; Montanari, Fernando; Quici, Silvio
Journal of the Chemical Society, Chemical Communications, 1989 , # 12 p. 779 - 780
反应条件
potassium tert-butylate in dimethyl sulfoxide T=20°C; Inert atmosphere;
参考文献
Molinaro, Carmela; Guilbault, Audrey-Anne; Kosjek, Birgit
Organic Letters, 2010 , vol. 12, # 17 p. 3772 - 3775
反应条件
3-chloro-benzenecarboperoxoic acid in dichloromethane T=0°C; 2 h;
参考文献
Fristrup, Peter; Dideriksen, Brian B.; Tanner, David; Norrby, Per-Ola
Journal of the American Chemical Society, 2005 , vol. 127, # 39 p. 13672 - 13679
反应条件
dihydrogen peroxide; 1,5-dicyclohexyl imidazole; Mn(III)-salophen in dichloromethane; N,N-dimethyl-formamide T=0°C; 1.25 h;
参考文献
Tetrahedron Letters, , vol. 47, # 12 p. 1923 - 1926
反应条件
1: (R)-phenylethylene oxide With sec.-butyllithium in tetrahydrofuran; hexane; cyclohexane T=-78°C; 0.000825 h; 2: methyl iodide in tetrahydrofuran; hexane; cyclohexane T=-78°C; 0.000555556 h;
参考文献
Nagaki, Aiichiro; Takizawa, Eiji; Yoshida, Jun-ichi
Journal of the American Chemical Society, 2009 , vol. 131, p. 1654 - 1655
反应条件
tetrachloromethane; 18-crown-6 ether in acetonitrile T=10°C;
参考文献
Journal of the American Chemical Society, , vol. 108, p. 539 - 541
反应条件
sec.-butyllithium; lithium bromide in tetrahydrofuran; diethyl ether; pentane T=-115°C; 1.5 h;
参考文献
Tarhouni, R.; Kirschleger, B.; Rambaud, M.; Villieras, J.
Tetrahedron Letters, 1984 , vol. 25, # 8 p. 835 - 838
反应条件
sodium hydride in tetrahydrofuran; dimethyl sulfoxide T=0 - 25°C; Corey-Chaykovsky reaction; 16 h;
参考文献
Ciaccio, James A.; Drahus, Antoinette L.; Meis, Regina M.; Tingle, Carice T.; Smrtka, Michael; Geneste, Richard
Synthetic Communications, 2003 , vol. 33, # 12 p. 2135 - 2143
反应条件
triphenylphosphine; diethylazodicarboxylate in benzene T=25°C; Elimination; 3 h;
参考文献
Tetrahedron Letters, , vol. 41, # 12 p. 1959 - 1962
反应条件
1: (R)-phenylethylene oxide; sec.-butyllithium in tetrahydrofuran; hexane; cyclohexane T=-78°C; 0.00661111 h; 2: methyl iodide in tetrahydrofuran; hexane; cyclohexane T=-78°C; 0.000555556 h;
参考文献
Journal of the American Chemical Society, , vol. 131, p. 1654 - 1655