1,2,3-三甲氧基丙烷合成路线 （共 13 条）
反应条件
1: glycerol With tetra(n-butyl)ammonium hydrogensulfate; potassium hydroxide T=20°C; 0.5 h; 2: dimethyl sulfate With potassium hydroxide T=15 - 20°C;
参考文献
Sutter, Marc; Pehlivan, Leyla; Lafon, Romain; Dayoub, Wissam; Raoul, Yann; Metay, Estelle; Lemaire, Marc
Green Chemistry, 2013 , vol. 15, # 11 p. 3020 - 3026
反应条件
sodium hydroxide in water T=100°C; 3 h;
参考文献
The United States of America as represented by the Secretary of Agriculture; Price, Neil P.
Patent: US8722943 B1, 2014 ;
Location in patent: Page/Page column 6 ;
反应条件
amberlyst-15 T=90°C; P=750.075 Torr; Product distribution / selectivity;
参考文献
Bhat, Ramanath N.; Bhat, Nayantara
Patent: US2007/260078 A1, 2007 ;
Location in patent: Page/Page column 5 ;
反应条件
sodium hydroxide in water T=70°C; 2 h;
参考文献
The United States of America as represented by the Secretary of Agriculture; Price, Neil P.
Patent: US8722943 B1, 2014 ;
Location in patent: Page/Page column 6; 7 ;
反应条件
1: epichlorohydrin With sodium in methanol 1 h; Inert atmosphereReflux; 2: dimethoxy glycerol in tetrahydrofuran; methanol; mineral oil 1 h; Inert atmosphereReflux; 3: methyl iodide in tetrahydrofuran; methanol; mineral oil T=20°C; Inert atmosphere;
参考文献
Herbert, Simon A.; Castell, Dominic C.; Clayden, Jonathan; Arnott, Gareth E.
Organic Letters, 2013 , vol. 15, # 13 p. 3334 - 3337
反应条件
trifluorormethanesulfonic acid; aqua(2,2'-bipyridine)(η5-pentamethylcyclopentadienyl)ruthenium(II) triflate; hydrogen in sulfolane T=200°C; P=25877.6 Torr; 3.5 h; Autoclave;
参考文献
Thibault, Michelle E.; Dimondo, Domenico V.; Jennings, Michael; Abdelnur, Patricia Verardi; Eberlin, Marcos N.; Schlaf, Marcel
Green Chemistry, 2011 , vol. 13, # 2 p. 357 - 366
反应条件
1: glycerol With tetra(n-butyl)ammonium hydrogensulfate; potassium hydroxide in neat (no solvent) T=20°C; 0.5 h; 2: methyl iodide in neat (no solvent) T=15 - 20°C; 24 h;
参考文献
Sutter, Marc; Dayoub, Wissam; Metay, Estelle; Raoul, Yann; Lemaire, Marc
ChemCatChem, 2013 , vol. 5, # 10 p. 2893 - 2904
反应条件
1: glycerol With tetra(n-butyl)ammonium hydrogensulfate; potassium hydroxide in tetrahydrofuran T=20°C; 0.5 h; 2: dimethyl sulfate in tetrahydrofuran T=15 - 20°C; 24 h; Solvent;
参考文献
Sutter, Marc; Dayoub, Wissam; Metay, Estelle; Raoul, Yann; Lemaire, Marc
ChemCatChem, 2013 , vol. 5, # 10 p. 2893 - 2904
反应条件
T=100°C; P=760 Torr; Electrolysis;
参考文献
Jiang, Tao; Liu, Chang-Jun; Fan, Guo-Liang
Chemistry Letters, 2001 , # 4 p. 322 - 323
反应条件
diethyl ether; boron trifluoride
参考文献
Mueller et al.
Zeitschrift fuer Naturforschung, 1959 , vol. 14b, p. 209
