1: With titanium(IV) isopropylate in toluene T=20 - 100°C; 2: With hydrogenchloride in diethyl ether; toluene

aluminum oxide; silica gel; potassium carbonate; sodium percarbonate; sodium salt of 2,4-dichloro-6-hydroxy-1,3,5-triazine in chloroform column chromatography;

chloroform; 10 Pd/C; hydrogen in methanol T=20°C; P=760.051 Torr; 2 h; chemoselective reaction;

hydrogenchloride in water 6 h;

1: With tri-ruthenium(0)dodecacarbonyl; (HSiMe2)2NH in toluene T=20 - 50°C; 24.17 h; Inert atmosphere; 2: With hydrogenchloride in 1,4-dioxane; ethyl acetate; toluene T=20°C; 0.5 h;

hydrogenchloride; water T=80°C; 2 h; Inert atmosphere;

bis(trimethylsilyl)-peroxide; dichlorotriphenylphosphorane in acetonitrile 60 h; Ambient temperature;

hydrogenchloride; sodium tetrahydroborate in water 3 h; Ambient temperature;

in acetonitrile T=25°C; 0.00266667 h; var. DBA conc. and reaction time; Rate constant;

in ethanol byproducts: SO2; addn. of S(N(CH2C6H5)2)2 soln. to soln. of CuCl2*2H2O in ethanol previously deoxygenated with nitrogen, reaction under oxygen free nitrogen; stirring at room temp.;; product mixt. in soln. obtained; pptn. of mixt. by addn. of cyclohexane; filtration; drying in vac.; white solid was isolated whose elem. anal. suggested a mixture of 65percent ((C6H5CH2)2NH2)(Cu2Cl3) and 35percent ((C6H5CH2(2NH2)Cl; IR spectroscopy;;