左旋-反式-1,2-环己二胺合成路线 （共 43 条）
反应条件
hydrogen; palladium dihydroxide in methanol T=20°C; P=2068.59 Torr; 48 h;
参考文献
Chandrasekhar; Sekar; Singh
Tetrahedron Letters, 2000 , vol. 41, # 51 p. 10079 - 10083
参考文献
Bulletin of the Chemical Society of Japan, , vol. 66, # 7 p. 2002 - 2005
Acta Chemica Scandinavica, , vol. 50, # 10 p. 918 - 921
反应条件
in water T=70°C; Resolution of racemate; optical yield given as percent ee;
参考文献
Stead, Darren; O'Brien, Peter; Sanderson, Adam
Organic Letters, 2008 , vol. 10, # 7 p. 1409 - 1412
反应条件
Candida antarctica lipase on acrylic resin in 1,4-dioxane T=20°C;
参考文献
Tumambac, Gilbert E.; Wolf, Christian
Organic Letters, 2005 , vol. 7, # 18 p. 4045 - 4048
反应条件
1: With L-(+)-tartaric acid; acetic acid in methanol; water 24 h; Heating; 2: With hydrogenchloride in acetone 25 h; Heating; 3: With sodium hydroxide
参考文献
Tetrahedron Asymmetry, , vol. 14, # 18 p. 2763 - 2769
反应条件
potassium carbonate in ethanol T=70 - 80°C; 2 h;
参考文献
Tetrahedron Asymmetry, , vol. 12, # 3 p. 433 - 437
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 233, p. 97,98
Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen, Series B: Physical Sciences, , vol. 40, p. 12
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 233, p. 97,99
反应条件
1: 95 percent / LiClO4 / acetonitrile / 48 h / 20 °C 2: 75 percent / diisopropyl azodicarboxylate; Ph3P / CH2Cl2 / 7 h / 0 - 20 °C 3: TMSN3 / acetonitrile / 7 h / 20 °C 4: 95 percent / H2 / Pd(OH)2/C / methanol / 48 h / 20 °C / 2068.59 Torr View Scheme
参考文献
Tetrahedron Letters, , vol. 41, # 51 p. 10079 - 10083
反应条件
1: TMSN3 / acetonitrile / 7 h / 20 °C 2: 95 percent / H2 / Pd(OH)2/C / methanol / 48 h / 20 °C / 2068.59 Torr View Scheme
参考文献
Tetrahedron Letters, , vol. 41, # 51 p. 10079 - 10083
反应条件
1: 75 percent / diisopropyl azodicarboxylate; Ph3P / CH2Cl2 / 7 h / 0 - 20 °C 2: TMSN3 / acetonitrile / 7 h / 20 °C 3: 95 percent / H2 / Pd(OH)2/C / methanol / 48 h / 20 °C / 2068.59 Torr View Scheme
参考文献
Tetrahedron Letters, , vol. 41, # 51 p. 10079 - 10083
