1-碘-1H,1H,2H,2H-全氟辛烷合成路线 （共 102 条）
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
piperidin-2-one; water; potassium carbonate 1) 140 deg C, 5 h, 2) EtOH, CHCl3, 60 deg C, 4.5 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Brace
Journal of Organic Chemistry, 1996 , vol. 61, # 19 p. 6504 - 6516
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
in toluene 5.5 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Brace
Journal of Organic Chemistry, 1995 , vol. 60, # 7 p. 2059 - 2071
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 6-7; 8-9 ;
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇
反应条件
sodium hydroxide; water 1.) 140 degC, 6 h; 2.)62-85 degC, 22 h; Yield given. Multistep reaction;
参考文献
Brace, Neal O.
Journal of Fluorine Chemistry, 1986 , vol. 31, p. 151 - 174
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇
反应条件
N-methyl-formamide Yield given. Yields of byproduct given;
参考文献
Brace, Neal O.
Journal of Fluorine Chemistry, 1985 , vol. 29, p. 119
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water T=140°C; 8 h; other temperatures, duration, the effect of mole ratios; Rate constantProduct distributionMechanism;
参考文献
Journal of Organic Chemistry, , vol. 61, # 19 p. 6504 - 6516
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇
反应条件
Yield given. Yields of byproduct given;
参考文献
Brace, Neal O.
Journal of Fluorine Chemistry, 1985 , vol. 29, p. 119
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water T=140°C; 1 h; var. temp., time, substrate (DMF, 1,2-ethanyl-bis-formamide) investigated; Product distributionRate constant;
参考文献
Brace, Neal O.
Journal of Fluorine Chemistry, 1986 , vol. 31, p. 151 - 174
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water Product distribution;
参考文献
Journal of Fluorine Chemistry, , vol. 29, p. 119
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
T=140°C; 1 h; other times; also with ε-caprolactam; Rate constantMechanism;
参考文献
Brace
Journal of Organic Chemistry, 1995 , vol. 60, # 7 p. 2059 - 2071
