1,1,2,2-四氢全氟己基碘合成路线 （共 24 条）
反应条件
T=205°C; Addition; 24 h;
参考文献
Balague; Ameduri; Boutevin; Caporiccio
Journal of Fluorine Chemistry, 2000 , vol. 102, # 1-2 p. 253 - 268
反应条件
1: 1.) NaN3, 2.) N2H4*H2O-Raney Ni 2: 89 percent / 15 h / 40 - 45 °C View Scheme
参考文献
Roman; Szoenyi; Bracon; Cambon
Synthetic Communications, 1997 , vol. 27, # 18 p. 3125 - 3132
反应条件
1: 1-iodo-3,3,4,4,5,5,6,6,6-nonafluorohexane; triethyl phosphite T=150°C; 16 h; 2: triethyl phosphite 2 h; 3: triethyl phosphite 24 h;
参考文献
3M INNOVATIVE PROPERTIES COMPANY
Patent: WO2003/102003 A1, 2003 ;
Location in patent: Page 7 ;
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; silver nitrate; copper(II) sulfate T=180°C; Gas phase; Conversion of starting material;
参考文献
Daikin Industries, Ltd.
Patent: US6664430 B1, 2003 ;
Location in patent: Page column 8-9 ;
反应条件
(10H)-phenothiazine in tert-butyl alcohol T=160°C; 6 h;
参考文献
Asahi Glass Company, Limited
Patent: EP1486482 A1, 2004 ;
Location in patent: Page 5; 6 ;
反应条件
hydrogenchloride; formic acid; oxygen; copper; zinc in water T=80°C; 2 h; various solvents, water concentration; Product distribution;
参考文献
Blancou,H.; Benefice,S.
Journal of Fluorine Chemistry, 1983 , vol. 23, p. 57
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; silver nitrate; copper(II) sulfate T=180°C; Gas phase; Conversion of starting material;
参考文献
Daikin Industries, Ltd.
Patent: US6664430 B1, 2003 ;
Location in patent: Page column 8-9 ;
反应条件
(10H)-phenothiazine in tert-butyl alcohol T=160°C; 6 h;
参考文献
EP1486482 A1, ;
Page 5; 6 ;
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; silver nitrate; copper(II) sulfate T=180°C; Gas phase; Conversion of starting material;
参考文献
Daikin Industries, Ltd.
Patent: US6664430 B1, 2003 ;
Location in patent: Page column 8-9 ;
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; silver nitrate; copper(II) sulfate T=180°C; Gas phase; Conversion of starting material;
参考文献
Daikin Industries, Ltd.
Patent: US6664430 B1, 2003 ;
Location in patent: Page column 8-9 ;
