1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷合成路线 （共 87 条）
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
potassium hydroxide T=100°C; 4 h; Product distribution / selectivity;
参考文献
Andrews, Mark Allen; Shtarov, Alexander Borisovich; Hockman, Joseph Norman
Patent: US2007/123731 A1, 2007 ;
Location in patent: Page/Page column 6 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
T=100°C; 4 h; Product distribution / selectivity;
参考文献
Andrews, Mark Allen; Shtarov, Alexander Borisovich; Hockman, Joseph Norman
Patent: US2007/123731 A1, 2007 ;
Location in patent: Page/Page column 6 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 6-7; 8-9 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
T=100°C; 4 h; Product distribution / selectivity;
参考文献
Andrews, Mark Allen; Shtarov, Alexander Borisovich; Hockman, Joseph Norman
Patent: US2007/123731 A1, 2007 ;
Location in patent: Page/Page column 5 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
17741-60-53,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十一氟十二烷醇丙烯酸酯
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 7-8 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 6-7; 8-9 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷
→
反应条件
sodium azide in water; acetone 7 h; Heating;
参考文献
Gheorghe, Alexandru; Cuevas-Yanez, Erick; Horn, Joachim; Bannwarth, Willi; Narsaiah, Banda; Reiser, Oliver
Synlett, 2006 , # 17 p. 2767 - 2770
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
195324-88-01-溴-4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟癸基)苯
反应条件
1: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-iododecane With chloro-trimethyl-silane; ethylene dibromide; zinc in tetrahydrofuran
T=20°C; 15 h;
2: 4-bromo-1-iodobenzene in tetrahydrofuran
T=45°C; 12 h;
参考文献
Curran, Dennis P.; Oderaotoshi, Yoji
Tetrahedron, 2001 , vol. 57, # 24 p. 5243 - 5253
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
195324-88-01-溴-4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟癸基)苯
反应条件
1: p-bromophenyl bromide With magnesium in tetrahydrofuran
T=20°C; 24 h;
2: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-iododecane With di-.mu.-chloro-bis(1,5-cyclooctadiene)dicopper in tetrahydrofuran; diethyl ether
T=-5 - 20°C;
参考文献
Schneider, Siegfried; Bannwarth, Willi
Angewandte Chemie, International Edition, 2000 , vol. 39, # 22 p. 4142 - 4145
Angewandte Chemie, 2000 , vol. 112, p. 4293 - 4296
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷
→
89373-67-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一酰氯
反应条件
1: 1.) Mg / 1.) Et2O, 35 deg C, 2 h, 2.) Et2O, 5-10 deg C, 15 min
2: 92 percent / PCl5 / 1.) RT, 0.5 h, 2.) 110 deg C, 3 h
View Scheme
参考文献
Jouani, A. M.; Szoenyi, F.; Cambon, A.
Journal of Fluorine Chemistry, 1992 , vol. 56, # 1 p. 85 - 92
