1H,1H,2H,2H-全氟己-1-醇合成路线 （共 16 条）
反应条件
(10H)-phenothiazine in tert-butyl alcohol T=160°C; 6 h;
参考文献
EP1486482 A1, ;
Page 5; 6 ;
反应条件
1: With benzo[1,3,2]dioxaborole; [Rh[(R)-BINAP](COD)]BF4 in tetrahydrofuran T=0°C; 1 h; 2: With sodium hydroxide; dihydrogen peroxide in ethanol Further stages. Title compound not separated from byproducts.;
参考文献
Chemical Communications, , # 4 p. 464 - 465
反应条件
1: With Wilkinson's catalyst in tetrahydrofuran T=20°C; 2.5 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran Further stages. Title compound not separated from byproducts.;
参考文献
Organic Letters, , vol. 1, # 9 p. 1399 - 1402
反应条件
1: With Wilkinson's catalyst in tetrahydrofuran T=20°C; 1 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran Further stages. Title compound not separated from byproducts.;
参考文献
Organic Letters, , vol. 1, # 9 p. 1399 - 1402
反应条件
hydrogenchloride; water T=70°C; pH=0 - 1; 25 h;
参考文献
Paterova, Jana; Skalicky, Martin; Rybackova, Marketa; Kvicalova, Magdalena; Cvacka, Josef; Kvicala, Jaroslav
Journal of Fluorine Chemistry, 2010 , vol. 131, # 12 p. 1338 - 1343
反应条件
1: With bis(cyclohexanyl)borane in tetrahydrofuran T=20°C; 16 h; 2: With dihydrogen peroxide in tetrahydrofuran alkaline solution; Further stages.;
参考文献
Chemical Communications, , # 4 p. 386 - 387
反应条件
hydrogenchloride; formic acid; oxygen; copper; zinc in water T=80°C; 2 h; various solvents, water concentration; Product distribution;
参考文献
Blancou,H.; Benefice,S.
Journal of Fluorine Chemistry, 1983 , vol. 23, p. 57
反应条件
1: With (dichloro)hydroborane in hexane 2: With dihydrogen peroxide in hexane alkaline solution; Further stages.;
参考文献
Chemical Communications, , # 4 p. 386 - 387
反应条件
water; silver nitrate; copper(II) sulfate T=180°C; Gas phase; Conversion of starting material;
参考文献
US6664430 B1, ;
Page column 8-9 ;
反应条件
1: 3,3,4,4,5,5,6,6,6-nonafluorohexan-1-ol; acrylic acid With sodium carbonate; triethylamine; benzenesulfonyl chloride; Sumilizer GM in dichloromethane T=30 - 40°C; 2 h; 2: With water in dichloromethane 1 h; 3: acrylic acid With water; triethylamine; benzenesulfonyl chloride Product distribution / selectivity; more than 3 stages;
参考文献
US2009/23948 A1, ;
Page/Page column 5 ;
