酞菁二(吡啶)铁(II)络合物合成路线 （共 12 条）
反应条件
pyridine; dimethyl sulfoxide in dimethyl sulfoxide
Kinetics; to soln. of Fe-complex in DMSO was added soln. of pyridine in DMSO at 20+/-0.5°C; mechanism discussed;; detected by UV/VIS;;
参考文献
Pennesi, Giovanna; Ercolani, Claudio; Ascenzi, Paolo; Brunori, Maurizio; Monacelli, Fabrizio
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 1107 - 1112
反应条件
pyridine in pyridine
extd. with pyridine in a Soxhlet apparatus; pptd. with hexane, soln. in pyridine passed through alumina column, reprecipitated by hexane;
参考文献
Liston, David J.; Kennedy, Brendan J.; Murray, Keith S.; West, Bruce O.
Inorganic Chemistry, 1985 , vol. 24, p. 1561 - 1567
反应条件
pyridine in pyridine
room temp., in air;
参考文献
Ercolani, Claudio; Gardini, Marcello; Pennesi, Giovanna; Rossi, Gentilina
Journal of the Chemical Society, Chemical Communications, 1983 , # 10 p. 549 - 550
反应条件
pyridine in tetrachloromethane
Kinetics; a sublimed solid iron phthalocyanine film is dissolved in CCl4 using ultrasound, prepn. carried out in a drybox satd. with CCl4 to minimize theH2O content, addn. of pyridine to the stock soln., diln. (CCl4); not isolated, detn. by UV spectroscopy;
参考文献
Stymne, B.; Sauvage, F. X.; Wettermark, G.
Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, 1980 , vol. 36, p. 397 - 402
反应条件
pyridine; water in pyridine
Kinetics; byproducts: pyridinium chloride; in water-containing pyridine at 35.0+/-0.1°C;; not isolated; monitored by spectrophotometric and conductometric techniques;;
参考文献
Monacelli, Fabrizio
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , # 12 p. 3373 - 3380
反应条件
pyridine in dimethyl sulfoxide
Kinetics; to soln. of Fe-complex in DMSO was added soln. of pyridine in DMSO at 20°C; mechanism discussed;; not isolated, detected by UV/VIS;;
参考文献
Pennesi, Giovanna; Ercolani, Claudio; Rossi, Gentilina; Ascenzi, Paolo; Brunori, Maurizio; Monacelli, Fabrizio
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 1113 - 1118
反应条件
pyridine; triphenylphosphine in pyridine; toluene
N2-atmosphere; molar ratio Fe-complex:PPh3=1:1, room temp., stirring (48 h, pptn.); filtration;
参考文献
Ercolani, Claudio; Gardini, Marcello; Pennesi, Giovanna; Rossi, Gentilina
Journal of the Chemical Society, Chemical Communications, 1983 , # 10 p. 549 - 550
反应条件
in neat (no solvent)
on prolonged contact with N-base vapors;;
参考文献
Ercolani, Claudio; Gardini, Marcello; Murray, Keith S.; Pennesi, Giovanna; Rossi, Gentilina; Zwack, Peter R.
Inorganic Chemistry, 1987 , vol. 26, p. 3539 - 3543
反应条件
in pyridine; dichloromethane
redn. of (Fe(py)2Pc(2-))(1+) within a few days, especially in the daylight;
参考文献
Kalz, W.; Homborg, H.; Kueppers, H.; Kennedy, B. J.; Murray, K. S.
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1984 , vol. 39, # 11 p. 1478 - 1489
反应条件
in acetonitrile
a suspn. of complex in dry pyridine was heated in an evacuated glass ampoule at 160°C for 5 h, slowly cooled to room temp. (3°C/h); elem. anal.;
参考文献
Janczak, Jan; Kubiak, Ryszard
Inorganica Chimica Acta, 2003 , vol. 342, p. 64 - 76
